Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP

[Image: see text] We present a facile procedure for preparing thick (up to 300 nm) poly(3-sulfopropyl methacrylate) brushes using SI-ARGET-ATRP by conducting the reaction in a fluid film between the substrate and a coverslip. This method is advantageous in a number of ways: it does not require deoxy...

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Autores principales: Veldscholte, Lars B., de Beer, Sissi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496111/
https://www.ncbi.nlm.nih.gov/pubmed/37705713
http://dx.doi.org/10.1021/acsapm.3c01628
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author Veldscholte, Lars B.
de Beer, Sissi
author_facet Veldscholte, Lars B.
de Beer, Sissi
author_sort Veldscholte, Lars B.
collection PubMed
description [Image: see text] We present a facile procedure for preparing thick (up to 300 nm) poly(3-sulfopropyl methacrylate) brushes using SI-ARGET-ATRP by conducting the reaction in a fluid film between the substrate and a coverslip. This method is advantageous in a number of ways: it does not require deoxygenation of the reaction solution, and the monomer conversion is much higher than usual since only a minimal amount of solution (microliters) is used, resulting in a tremendous reduction (∼50×) of wasted reagents. Moreover, this method is particularly suitable for grafting brushes to large substrates.
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spelling pubmed-104961112023-09-13 Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP Veldscholte, Lars B. de Beer, Sissi ACS Appl Polym Mater [Image: see text] We present a facile procedure for preparing thick (up to 300 nm) poly(3-sulfopropyl methacrylate) brushes using SI-ARGET-ATRP by conducting the reaction in a fluid film between the substrate and a coverslip. This method is advantageous in a number of ways: it does not require deoxygenation of the reaction solution, and the monomer conversion is much higher than usual since only a minimal amount of solution (microliters) is used, resulting in a tremendous reduction (∼50×) of wasted reagents. Moreover, this method is particularly suitable for grafting brushes to large substrates. American Chemical Society 2023-08-24 /pmc/articles/PMC10496111/ /pubmed/37705713 http://dx.doi.org/10.1021/acsapm.3c01628 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Veldscholte, Lars B.
de Beer, Sissi
Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP
title Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP
title_full Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP
title_fullStr Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP
title_full_unstemmed Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP
title_short Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP
title_sort scalable air-tolerant μl-volume synthesis of thick poly(spma) brushes using si-arget-atrp
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496111/
https://www.ncbi.nlm.nih.gov/pubmed/37705713
http://dx.doi.org/10.1021/acsapm.3c01628
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