Insights into the Friedel–Crafts Benzoylation of N-Methylpyrrole inside the Confined Space of the Self-Assembled Resorcinarene Capsule

[Image: see text] Friedel–Crafts benzoylation of N-methylpyrrole 2 can run inside the confined space of the hexameric resorcinarene capsule C. The bridged water molecules at the corner of C act as H-bonding donor groups to polarize the C–Cl bond of benzoyl chlorides 3a–f. Confinement effects on the...

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Detalles Bibliográficos
Autores principales: Iuliano, Veronica, Talotta, Carmen, De Rosa, Margherita, Soriente, Annunziata, Neri, Placido, Rescifina, Antonio, Floresta, Giuseppe, Gaeta, Carmine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496122/
https://www.ncbi.nlm.nih.gov/pubmed/37641853
http://dx.doi.org/10.1021/acs.orglett.3c01935

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