Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes

[Image: see text] The functionalization of alkynylgermanes using hydrosilanes was accomplished by employing cobalt catalysis. Depending on the reactants used, the reaction can proceed via dehydrogenative coupling or hydrosilylation. Importantly, the presented method is characterized by mild reaction...

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Autores principales: Broniarz, Konstancja, Hreczycho, Grzegorz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496132/
https://www.ncbi.nlm.nih.gov/pubmed/37646486
http://dx.doi.org/10.1021/acs.orglett.3c02326
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author Broniarz, Konstancja
Hreczycho, Grzegorz
author_facet Broniarz, Konstancja
Hreczycho, Grzegorz
author_sort Broniarz, Konstancja
collection PubMed
description [Image: see text] The functionalization of alkynylgermanes using hydrosilanes was accomplished by employing cobalt catalysis. Depending on the reactants used, the reaction can proceed via dehydrogenative coupling or hydrosilylation. Importantly, the presented method is characterized by mild reaction conditions, allowing rapid access to a wide range of organogermanes.
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spelling pubmed-104961322023-09-13 Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes Broniarz, Konstancja Hreczycho, Grzegorz Org Lett [Image: see text] The functionalization of alkynylgermanes using hydrosilanes was accomplished by employing cobalt catalysis. Depending on the reactants used, the reaction can proceed via dehydrogenative coupling or hydrosilylation. Importantly, the presented method is characterized by mild reaction conditions, allowing rapid access to a wide range of organogermanes. American Chemical Society 2023-08-30 /pmc/articles/PMC10496132/ /pubmed/37646486 http://dx.doi.org/10.1021/acs.orglett.3c02326 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Broniarz, Konstancja
Hreczycho, Grzegorz
Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes
title Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes
title_full Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes
title_fullStr Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes
title_full_unstemmed Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes
title_short Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes
title_sort access to unsaturated organogermanes via (de)hydrosilylation mediated by cobalt complexes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496132/
https://www.ncbi.nlm.nih.gov/pubmed/37646486
http://dx.doi.org/10.1021/acs.orglett.3c02326
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