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Dynamic-dependent selectivity in a bisphosphine iron spin crossover C–H insertion/π-coordination reaction
Reaction pathway selectivity is generally controlled by competitive transition states. Organometallic reactions are complicated by the possibility that electronic spin state changes rather than transition states can control the relative rates of pathways, which can be modeled as minimum energy cross...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10498510/ https://www.ncbi.nlm.nih.gov/pubmed/37712027 http://dx.doi.org/10.1039/d3sc02078a |