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Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol
[Image: see text] The aim of this research was to examine the effect of strontium content in the MgAlO catalyst for the catalytic ethanol reaction on the product distribution. The structure of the catalysts and the actual amount of strontium on the catalysts were verified using XRD and ICP technique...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10500649/ https://www.ncbi.nlm.nih.gov/pubmed/37720756 http://dx.doi.org/10.1021/acsomega.3c03752 |
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author | Seekhiaw, Patchaporn Jantasee, Sasiradee Praserthdam, Piyasan Jongsomjit, Bunjerd |
author_facet | Seekhiaw, Patchaporn Jantasee, Sasiradee Praserthdam, Piyasan Jongsomjit, Bunjerd |
author_sort | Seekhiaw, Patchaporn |
collection | PubMed |
description | [Image: see text] The aim of this research was to examine the effect of strontium content in the MgAlO catalyst for the catalytic ethanol reaction on the product distribution. The structure of the catalysts and the actual amount of strontium on the catalysts were verified using XRD and ICP techniques, respectively. The acid and basic strength characteristics of catalysts were examined using NH(3)-TPD and CO(2)-TPD techniques, respectively. The strontium content was found to influence the textural properties and the acidic and basic characteristics of the catalysts, leading to differences in product selectivity and ethanol conversion. The MgAlO catalyst with 1.9 wt % strontium provided the maximum ethylene and butanol selectivity, probably due to the presence of appropriate medium acidic and strong basic sites. All catalysts can efficiently produce ethylene by a dehydration reaction and acetaldehyde by a dehydrogenation reaction. Acetaldehyde selectivity was dominant with increased strontium loading. |
format | Online Article Text |
id | pubmed-10500649 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-105006492023-09-15 Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol Seekhiaw, Patchaporn Jantasee, Sasiradee Praserthdam, Piyasan Jongsomjit, Bunjerd ACS Omega [Image: see text] The aim of this research was to examine the effect of strontium content in the MgAlO catalyst for the catalytic ethanol reaction on the product distribution. The structure of the catalysts and the actual amount of strontium on the catalysts were verified using XRD and ICP techniques, respectively. The acid and basic strength characteristics of catalysts were examined using NH(3)-TPD and CO(2)-TPD techniques, respectively. The strontium content was found to influence the textural properties and the acidic and basic characteristics of the catalysts, leading to differences in product selectivity and ethanol conversion. The MgAlO catalyst with 1.9 wt % strontium provided the maximum ethylene and butanol selectivity, probably due to the presence of appropriate medium acidic and strong basic sites. All catalysts can efficiently produce ethylene by a dehydration reaction and acetaldehyde by a dehydrogenation reaction. Acetaldehyde selectivity was dominant with increased strontium loading. American Chemical Society 2023-08-29 /pmc/articles/PMC10500649/ /pubmed/37720756 http://dx.doi.org/10.1021/acsomega.3c03752 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Seekhiaw, Patchaporn Jantasee, Sasiradee Praserthdam, Piyasan Jongsomjit, Bunjerd Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol |
title | Effect of Strontium
Modification in Mg–Al Mixed
Oxide Catalysts on Product Distribution toward Catalytic Reaction
of Ethanol |
title_full | Effect of Strontium
Modification in Mg–Al Mixed
Oxide Catalysts on Product Distribution toward Catalytic Reaction
of Ethanol |
title_fullStr | Effect of Strontium
Modification in Mg–Al Mixed
Oxide Catalysts on Product Distribution toward Catalytic Reaction
of Ethanol |
title_full_unstemmed | Effect of Strontium
Modification in Mg–Al Mixed
Oxide Catalysts on Product Distribution toward Catalytic Reaction
of Ethanol |
title_short | Effect of Strontium
Modification in Mg–Al Mixed
Oxide Catalysts on Product Distribution toward Catalytic Reaction
of Ethanol |
title_sort | effect of strontium
modification in mg–al mixed
oxide catalysts on product distribution toward catalytic reaction
of ethanol |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10500649/ https://www.ncbi.nlm.nih.gov/pubmed/37720756 http://dx.doi.org/10.1021/acsomega.3c03752 |
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