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Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol

[Image: see text] The aim of this research was to examine the effect of strontium content in the MgAlO catalyst for the catalytic ethanol reaction on the product distribution. The structure of the catalysts and the actual amount of strontium on the catalysts were verified using XRD and ICP technique...

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Autores principales: Seekhiaw, Patchaporn, Jantasee, Sasiradee, Praserthdam, Piyasan, Jongsomjit, Bunjerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10500649/
https://www.ncbi.nlm.nih.gov/pubmed/37720756
http://dx.doi.org/10.1021/acsomega.3c03752
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author Seekhiaw, Patchaporn
Jantasee, Sasiradee
Praserthdam, Piyasan
Jongsomjit, Bunjerd
author_facet Seekhiaw, Patchaporn
Jantasee, Sasiradee
Praserthdam, Piyasan
Jongsomjit, Bunjerd
author_sort Seekhiaw, Patchaporn
collection PubMed
description [Image: see text] The aim of this research was to examine the effect of strontium content in the MgAlO catalyst for the catalytic ethanol reaction on the product distribution. The structure of the catalysts and the actual amount of strontium on the catalysts were verified using XRD and ICP techniques, respectively. The acid and basic strength characteristics of catalysts were examined using NH(3)-TPD and CO(2)-TPD techniques, respectively. The strontium content was found to influence the textural properties and the acidic and basic characteristics of the catalysts, leading to differences in product selectivity and ethanol conversion. The MgAlO catalyst with 1.9 wt % strontium provided the maximum ethylene and butanol selectivity, probably due to the presence of appropriate medium acidic and strong basic sites. All catalysts can efficiently produce ethylene by a dehydration reaction and acetaldehyde by a dehydrogenation reaction. Acetaldehyde selectivity was dominant with increased strontium loading.
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spelling pubmed-105006492023-09-15 Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol Seekhiaw, Patchaporn Jantasee, Sasiradee Praserthdam, Piyasan Jongsomjit, Bunjerd ACS Omega [Image: see text] The aim of this research was to examine the effect of strontium content in the MgAlO catalyst for the catalytic ethanol reaction on the product distribution. The structure of the catalysts and the actual amount of strontium on the catalysts were verified using XRD and ICP techniques, respectively. The acid and basic strength characteristics of catalysts were examined using NH(3)-TPD and CO(2)-TPD techniques, respectively. The strontium content was found to influence the textural properties and the acidic and basic characteristics of the catalysts, leading to differences in product selectivity and ethanol conversion. The MgAlO catalyst with 1.9 wt % strontium provided the maximum ethylene and butanol selectivity, probably due to the presence of appropriate medium acidic and strong basic sites. All catalysts can efficiently produce ethylene by a dehydration reaction and acetaldehyde by a dehydrogenation reaction. Acetaldehyde selectivity was dominant with increased strontium loading. American Chemical Society 2023-08-29 /pmc/articles/PMC10500649/ /pubmed/37720756 http://dx.doi.org/10.1021/acsomega.3c03752 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Seekhiaw, Patchaporn
Jantasee, Sasiradee
Praserthdam, Piyasan
Jongsomjit, Bunjerd
Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol
title Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol
title_full Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol
title_fullStr Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol
title_full_unstemmed Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol
title_short Effect of Strontium Modification in Mg–Al Mixed Oxide Catalysts on Product Distribution toward Catalytic Reaction of Ethanol
title_sort effect of strontium modification in mg–al mixed oxide catalysts on product distribution toward catalytic reaction of ethanol
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10500649/
https://www.ncbi.nlm.nih.gov/pubmed/37720756
http://dx.doi.org/10.1021/acsomega.3c03752
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