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Targeted Synthesis of End-On Dinitrogen-Bridged Lanthanide Metallocenes and Their Reactivity as Divalent Synthons
[Image: see text] High-yield syntheses of the lanthanide dinitrogen complexes [(Cp(2)(ttt)M)(2)(μ-1,2-N(2))] (1(M), M = Gd, Tb, Dy; Cp(ttt) = 1,2,4-C(5)(t)Bu(3)H(2)), in which the [N(2)](2–) ligands solely adopt the rare end-on or 1,2-bridging mode, are reported. The bulk of the tert-butyl substitue...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510326/ https://www.ncbi.nlm.nih.gov/pubmed/37656516 http://dx.doi.org/10.1021/jacs.3c07600 |