Direct Visualization of the Charge Transfer in a Graphene/α-RuCl(3) Heterostructure via Angle-Resolved Photoemission Spectroscopy

[Image: see text] We investigate the electronic properties of a graphene and α-ruthenium trichloride (α-RuCl(3)) heterostructure using a combination of experimental techniques. α-RuCl(3) is a Mott insulator and a Kitaev material. Its combination with graphene has gained increasing attention due to its potential applicability in novel optoelectronic devices. By using a combination of spatially resolved photoemission spectroscopy and low-energy electron microscopy, we are able to provide a direct visualization of the massive charge transfer from graphene to α-RuCl(3), which can modify the electronic properties of both materials, leading to novel electronic phenomena at their interface. A measurement of the spatially resolved work function allows for a direct estimate of the interface dipole between graphene and α-RuCl(3). Their strong coupling could lead to new ways of manipulating electronic properties of a two-dimensional heterojunction. Understanding the electronic properties of this structure is pivotal for designing next generation low-power optoelectronics devices.