Site selective gold(i)-catalysed benzylic C–H amination via an intermolecular hydride transfer to triazolinediones

Triazolinediones are known as highly reactive dienophiles that can also act as electrophilic amination reagents towards enolisable C–H bonds (ionic pathway) or weak C–H bonds (free radical pathway). Here, we report that this C–H amination reactivity can be significantly extended and enhanced via gol...

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Detalles Bibliográficos
Autores principales: Bevernaege, Kevin, Tzouras, Nikolaos V., Poater, Albert, Cavallo, Luigi, Nolan, Steven P., Nahra, Fady, Winne, Johan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510626/
https://www.ncbi.nlm.nih.gov/pubmed/37736629
http://dx.doi.org/10.1039/d3sc03683a

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