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CsPbCl(3) → CsPbI(3) Exchange in Perovskite Nanocrystals Proceeds through a Jump-the-Gap Reaction Mechanism

[Image: see text] Halide exchange is a popular strategy to tune the properties of CsPbX(3) nanocrystals after synthesis. However, while Cl → Br and Br → I exchanges proceed through the formation of stable mixed-halide nanocrystals, the Cl ⇌ I exchange is more elusive. Indeed, the large size differen...

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Detalles Bibliográficos
Autores principales: Livakas, Nikolaos, Toso, Stefano, Ivanov, Yurii P., Das, Tisita, Chakraborty, Sudip, Divitini, Giorgio, Manna, Liberato
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10515632/
https://www.ncbi.nlm.nih.gov/pubmed/37691231
http://dx.doi.org/10.1021/jacs.3c06214