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Iron-Catalyzed Synthesis of α-Azido α-Amino Esters via the Alkylazidation of Alkenes
[Image: see text] An iron-catalyzed alkylazidation of dehydroamino acids using peroxides as alkyl radical precursors is described. Non-natural azidated amino esters bearing an α-alkyl chain could be obtained in 18–94% yields using TMSN(3) as an azide source. The obtained α-alkyl-α-azide α-amino este...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10521020/ https://www.ncbi.nlm.nih.gov/pubmed/37684011 http://dx.doi.org/10.1021/acs.orglett.3c02153 |