Coordination of ε-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination–Insertion

[Image: see text] We report three niobium-based initiators for the catalytic ring-opening polymerization (ROP) of ε-caprolactone, exhibiting good activity and molecular weight control. In particular, we have prepared on the gram-scale and fully characterized a monometallic cationic alkoxo-Nb(V) ε-ca...

Descripción completa

Detalles Bibliográficos
Autores principales: Buchard, Antoine, Davidson, Matthew G., Gobius du Sart, Gerrit, Jones, Matthew D., Kociok-Köhn, Gabriele, McCormick, Strachan N., Mckeown, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10523432/
https://www.ncbi.nlm.nih.gov/pubmed/37695575
http://dx.doi.org/10.1021/acs.inorgchem.3c02491

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10523432/
https://www.ncbi.nlm.nih.gov/pubmed/37695575
http://dx.doi.org/10.1021/acs.inorgchem.3c02491

Ejemplares similares