Cargando…

Coordination of ε-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination–Insertion

[Image: see text] We report three niobium-based initiators for the catalytic ring-opening polymerization (ROP) of ε-caprolactone, exhibiting good activity and molecular weight control. In particular, we have prepared on the gram-scale and fully characterized a monometallic cationic alkoxo-Nb(V) ε-ca...

Descripción completa

Detalles Bibliográficos
Autores principales:	Buchard, Antoine, Davidson, Matthew G., Gobius du Sart, Gerrit, Jones, Matthew D., Kociok-Köhn, Gabriele, McCormick, Strachan N., Mckeown, Paul
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10523432/ https://www.ncbi.nlm.nih.gov/pubmed/37695575 http://dx.doi.org/10.1021/acs.inorgchem.3c02491

Ejemplares similares

A Highly Active and Selective Zirconium-Based Catalyst System for the Industrial Production of Poly(lactic acid)
por: Buchard, Antoine, et al.
Publicado: (2023)

Crystallization of Poly(ε-caprolactone) in Poly(vinylidene fluoride)/Poly(ε-caprolactone) Blend
por: Kong, Yang, et al.
Publicado: (2017)

The role of coordination strength in solid polymer electrolytes: compositional dependence of transference numbers in the poly(ε-caprolactone)–poly(trimethylene carbonate) system
por: Eriksson, Therese, et al.
Publicado: (2021)

Preparation and in vitro characterization of retinoic acid-loaded poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) micelles
por: Shakiba, Ebrahim, et al.
Publicado: (2017)

The Application of Polycaprolactone Scaffolds with Poly(ε-caprolactone)–Poly(ethylene glycol)–Poly(ε-caprolactone) Loaded on Kidney Cell Culture
por: Sun, Junyu, et al.
Publicado: (2022)

Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group
por: Czakler, Matthias, et al.
Publicado: (2012)

Orthogonal Templating Control of the Crystallisation of Poly(ε-Caprolactone)
por: Mitchell, Geoffrey R., et al.
Publicado: (2018)

Radical Ring Opening Polymerization of Cyclic Ketene Acetals Derived From d-Glucal
por: Hardy, Craig, et al.
Publicado: (2023)

Mesoporous magnesium silicate-incorporated poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) bioactive composite beneficial to osteoblast behaviors
por: Niu, Yunfei, et al.
Publicado: (2014)

Cationic Niobium‐Sandwich and Piano‐Stool Complexes
por: Unkrig, Wiebke, et al.
Publicado: (2020)

Coordination Polymers Containing 1,3-Phenylenebis-((1H-1,2,4-triazol-1-yl)methanone) Ligand: Synthesis and ε-Caprolactone Polymerization Behavior
por: Bello-Vieda, Nestor J., et al.
Publicado: (2017)

Modification of aluminium alkoxides with dialkylmalonates
por: Lichtenberger, Robert, et al.
Publicado: (2010)

Preparation and characterization of polylactide/poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) hybrid fibers for potential application in bone tissue engineering
por: Wang, YueLong, et al.
Publicado: (2014)

Properties of Electrospun Nanofibers of Multi-Block Copolymers of [Poly-ε-caprolactone-b-poly(tetrahydrofuran-co-ε-caprolactone)](m) Synthesized by Janus Polymerization
por: Shah, Muhammad Ijaz, et al.
Publicado: (2017)

Fibrous Materials Made of Poly(ε-caprolactone)/Poly(ethylene oxide)-b-Poly(ε-caprolactone) Blends Support Neural Stem Cells Differentiation
por: Fernández, Daniel, et al.
Publicado: (2019)

Quo vadis niobium? Divergent coordination behavior of early-transition metals towards MOF-5
por: Korzyński, Maciej D., et al.
Publicado: (2019)

Formulation, and Evaluation of Pentoxifylline-Loaded Poly(ε-caprolactone) Microspheres
por: Tamizharasi, S., et al.
Publicado: (2008)

Precise Synthesis, Properties, and Structures of Cyclic Poly(ε-caprolactone)s
por: Xiang, Li, et al.
Publicado: (2018)

Remote Outcomes with Poly-ε-Caprolactone Aortic Grafts in Rats
por: Dokuchaeva, Anna A., et al.
Publicado: (2023)

NacNac-zinc-pyridonate mediated ε-caprolactone ROP
por: Hughes, Jack W. J., et al.
Publicado: (2023)

Biodegradable In Situ Gel-Forming Controlled Drug Delivery System Based on Thermosensitive Poly(ε-caprolactone)-Poly(ethylene glycol)-Poly(ε-caprolactone) Hydrogel
por: Khodaverdi, Elham, et al.
Publicado: (2012)

Sustained Release of Vascular Endothelial Growth Factor from Poly(ε-caprolactone-PEG-ε-caprolactone)-b-Poly(l-lactide) Multiblock Copolymer Microspheres
por: Scheiner, Karina C., et al.
Publicado: (2019)

Melt Crystallization Behavior and Crystalline Morphology of Polylactide/Poly(ε-caprolactone) Blends Compatibilized by Lactide-Caprolactone Copolymer
por: Zhang, Chunmei, et al.
Publicado: (2018)

Effect of Composition on the Crystallization, Water Absorption, and Biodegradation of Poly(ε-caprolactam-co-ε-caprolactone) Copolymers
por: Dou, Yuanyuan, et al.
Publicado: (2020)

A novel Poly(ε-caprolactone)-Pluronic-Poly(ε-caprolactone) grafted Polyethyleneimine(PCFC-g-PEI), Part 1, synthesis, cytotoxicity, and in vitro transfection study
por: Shi, Shuai, et al.
Publicado: (2009)

Selected Physicochemical and Pharmaceutical Properties of Poly-ε-caprolactone and Poly(d,l-lactide-co-ε-caprolactone) Conjugates of Lamivudine Synthesized via Ring-Opening Polymerization
por: Urbaniak, Tomasz, et al.
Publicado: (2019)

Structural and Dynamic Properties of Gallium Alkoxides
por: Mears, Kristian L., et al.
Publicado: (2019)

Controlling oxygen coordination and valence of network forming cations
por: Aoyagi, Takuya, et al.
Publicado: (2020)

A linear Di-coordinate boron radical cation
por: Lin, Yu-Jiang, et al.
Publicado: (2022)

Novel hybrid membrane of chitosan/poly (ε-caprolactone) for tissue engineering
por: Cardoso, Guinea BC, et al.
Publicado: (2014)

Poly(Trimethylene Carbonate-co-ε-Caprolactone) Promotes Axonal Growth
por: Rocha, Daniela Nogueira, et al.
Publicado: (2014)

Ring-opening copolymerization thermodynamics and kinetics of γ-valerolactone/ϵ-caprolactone
por: Gagliardi, Mariacristina, et al.
Publicado: (2018)

Influence of the Cross-Link Density on the Rate of Crystallization of Poly(ε-Caprolactone)
por: Sedov, Igor, et al.
Publicado: (2018)

Enzymatic Degradation of Star Poly(ε-Caprolactone) with Different Central Units
por: Blackwell, Catherine J., et al.
Publicado: (2018)

Novel Zinc-Catalytic Systems for Ring-Opening Polymerization of ε-Caprolactone
por: Żółtowska, Karolina, et al.
Publicado: (2015)

Impact of Various Sterilization and Disinfection Techniques on Electrospun Poly-ε-caprolactone
por: Horakova, Jana, et al.
Publicado: (2020)

PEGylated Amine-Functionalized Poly(ε-caprolactone) for the Delivery of Plasmid DNA
por: Jafari, Amin, et al.
Publicado: (2020)

The Drug-Loaded Electrospun Poly(ε-Caprolactone) Mats for Therapeutic Application
por: Opálková Šišková, Alena, et al.
Publicado: (2021)

Crystal Nucleation and Growth in Cross-Linked Poly(ε-caprolactone) (PCL)
por: Mukhametzyanov, Timur, et al.
Publicado: (2021)

Radiation Processing of Styrene-isoprene-styrene/Poly(ε-caprolactone) Blends
por: Lungulescu, Eduard-Marius, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_jvhs9rijc481l0lip3acb0r5cl