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Manipulating Ligand Density at the Surface of Polyoxovanadate-Alkoxide Clusters

[Image: see text] We present the post-synthetic modification of a polyoxovanadate-alkoxide (POV-alkoxide) cluster via the reactivity of its cationic form, [V(6)O(7)(OCH(3))(12)](1+), with water. This result indicates that cluster oxidation increases the lability of bridging methoxide ligands, afford...

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Detalles Bibliográficos
Autores principales:	Marinho, Thompson V., Schreiber, Eric, Garwick, Rachel E., Brennessel, William W., Matson, Ellen M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10523436/ https://www.ncbi.nlm.nih.gov/pubmed/37712579 http://dx.doi.org/10.1021/acs.inorgchem.3c02314

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