Cargando…

Unexpected Latency of Z-Stereoretentive Ruthenium Olefin Metathesis Catalysts Bearing Unsymmetrical N-heterocyclic Carbene or Cyclic(alkyl)(amino)carbene Ligands

[Image: see text] A set of ruthenium complexes bearing a CAAC or uNHC ligand and a dithiocatechol fragment have been obtained and characterized spectroscopically. The activity and Z-selectivity of the newly obtained catalysts were studied in selected model CM, self-CM, and RCM olefin metathesis reac...

Descripción completa

Detalles Bibliográficos
Autores principales:	Grzesiński, Łukasz, Milewski, Mariusz, Nadirova, Maryana, Kajetanowicz, Anna, Grela, Karol
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10526643/ https://www.ncbi.nlm.nih.gov/pubmed/37772273 http://dx.doi.org/10.1021/acs.organomet.2c00428

Ejemplares similares

Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N‐Heterocyclic Carbene Ligand: Improved Stability and Activity
por: Kośnik, Wioletta, et al.
Publicado: (2022)

The Influence of Various N-Heterocyclic Carbene Ligands on Activity of Nitro-Activated Olefin Metathesis Catalysts
por: Pieczykolan, Michał, et al.
Publicado: (2020)

Sterically Tuned N-Heterocyclic Carbene Ligands for the Efficient Formation of Hindered Products in Ru-Catalyzed Olefin Metathesis
por: Planer, Sebastian, et al.
Publicado: (2020)

Ruthenium Olefin Metathesis Catalysts Featuring N-Heterocyclic Carbene Ligands Tagged with Isonicotinic and 4-(Dimethylamino)benzoic Acid Rests: Evaluation of a Modular Synthetic Strategy
por: Czarnocki, Stefan, et al.
Publicado: (2021)

Catalytic Decomposition of Long‐Chain Olefins to Propylene via Isomerization‐Metathesis Using Latent Bicyclic (Alkyl)(Amino)Carbene‐Ruthenium Olefin Metathesis Catalysts
por: Nagyházi, Márton, et al.
Publicado: (2022)

Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
por: Gawin, Rafał, et al.
Publicado: (2016)

Using stereoretention for the synthesis of E-macrocycles with ruthenium-based olefin metathesis catalysts
por: Ahmed, Tonia S., et al.
Publicado: (2018)

A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts
por: Müller, Daniel S, et al.
Publicado: (2018)

Mesomeric Acceleration Counters Slow Initiation of Ruthenium–CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene)
por: Ou, Xinrui, et al.
Publicado: (2023)

Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions
por: Kajetanowicz, Anna, et al.
Publicado: (2020)

Looking for the Noncyclic(amino)(alkyl)carbene Ruthenium Catalyst for Ethenolysis of Ethyl Oleate: Selectivity Is on Target
por: Wyrębek, Przemysław, et al.
Publicado: (2018)

Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium−Carbene Catalysts
por: Nascimento, Daniel L., et al.
Publicado: (2021)

Mechanism of Olefin Metathesis with Neutral and Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
por: Herz, Katharina, et al.
Publicado: (2019)

Ene–yne cross-metathesis with ruthenium carbene catalysts
por: Fischmeister, Cédric, et al.
Publicado: (2011)

Light‐Driven gem Hydrogenation: An Orthogonal Entry into “Second‐Generation” Ruthenium Carbene Catalysts for Olefin Metathesis
por: Zachmann, Raphael J., et al.
Publicado: (2021)

Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
por: Paradiso, Veronica, et al.
Publicado: (2018)

Ruthenium Carbene Mediated Metathesis of Oleate-Type Fatty Compounds
por: Marvey, Bassie B., et al.
Publicado: (2008)

Heterobimetallic Coinage Metal‐Ruthenium Complexes Supported by Anionic N‐Heterocyclic Carbenes
por: Planer, Sebastian, et al.
Publicado: (2021)

Modified N-Heterocyclic Carbene Ligand for the Recovery of Olefin Metathesis Catalysts via Noncovalent Host–Guest Interactions
por: Ondrusek, Brian A., et al.
Publicado: (2017)

Synthesis and Catalytic Properties of a Very Latent Selenium-Chelated Ruthenium Benzylidene Olefin Metathesis Catalyst
por: Monsigny, Louis, et al.
Publicado: (2021)

A tunable family of CAAC-ruthenium olefin metathesis catalysts modularly derived from a large-scale produced ibuprofen intermediate
por: Sytniczuk, Adrian, et al.
Publicado: (2023)

Grubbs–Hoveyda type catalysts bearing a dicationic N-heterocyclic carbene for biphasic olefin metathesis reactions in ionic liquids
por: Koy, Maximilian, et al.
Publicado: (2015)

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?
por: Gehrke, Sascha, et al.
Publicado: (2020)

New metathesis catalyst bearing chromanyl moieties at the N-heterocyclic carbene ligand
por: Hryniewicka, Agnieszka, et al.
Publicado: (2015)

Activation of Ge−H and Sn−H Bonds with N‐Heterocyclic Carbenes and a Cyclic (Alkyl)(amino)carbene
por: Philipp, Michael S. M., et al.
Publicado: (2022)

N-Heterocyclic carbenes
por: Nolan, Steven P
Publicado: (2015)

The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition
por: Occhipinti, Giovanni, et al.
Publicado: (2022)

Olefin Metathesis in Continuous Flow Reactor Employing Polar Ruthenium Catalyst and Soluble Metal Scavenger for Instant Purification of Products of Pharmaceutical Interest
por: Toh, Ren Wei, et al.
Publicado: (2021)

Enantioselective N-heterocyclic carbene-catalyzed nucleophilic dearomatization of alkyl pyridiniums
por: Flanigan, Darrin M., et al.
Publicado: (2017)

Enantioselective S(N)2 Alkylation of Homoenolates by N‐Heterocyclic Carbene Catalysis
por: Li, En, et al.
Publicado: (2023)

Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
por: Seed, John A., et al.
Publicado: (2017)

The influence of the cationic carbenes on the initiation kinetics of ruthenium-based metathesis catalysts; a DFT study
por: Jawiczuk, Magdalena, et al.
Publicado: (2018)

Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene
por: Urbina-Blanco, César A, et al.
Publicado: (2010)

Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts
por: Benedikter, Mathis J., et al.
Publicado: (2020)

Preparation of Functionalized α,β-Unsaturated Sulfonamides via Olefin Cross-Metathesis
por: Woźniak, Łukasz, et al.
Publicado: (2020)

Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support
por: Tyszka-Gumkowska, Agata, et al.
Publicado: (2022)

Unsymmetric N-heterocyclic carbene ligand enabled nickel-catalysed arylation of bulky primary and secondary amines
por: Wang, Zi-Chao, et al.
Publicado: (2023)

Hydrogenative Metathesis of Enynes via Piano-Stool Ruthenium Carbene Complexes Formed by Alkyne gem-Hydrogenation
por: Peil, Sebastian, et al.
Publicado: (2020)

Enantioselective Olefin Metathesis with Cyclometalated Ruthenium Complexes
por: Hartung, John, et al.
Publicado: (2014)

Unsaturated Copolyesters from Macrolactone/Norbornene: Toward Reaction Kinetics of Metathesis Copolymerization Using Ruthenium Carbene Catalysts
por: Martínez, Araceli, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_u3j1d5pl368fkqpm5h5h8sh11o