Chemical Corrosion-Water-Confining Pressure Coupling Damage Constitutive Model of Rock Based on the SMP Strength Criterion

Aiming at the problem of chemical-mechanics-hydro (C-M-H) action encountered by rocks in underground engineering, chemical damage variables, water damage variables, and force damage variables are introduced to define the degree of degradation of rock materials. Stone is selected as the sample for acid corrosion treatment at pH 3, 4, and 7, and a chemical damage factor is defined that coupled the pH value and duration of exposure. Then based on the spatial mobilized plane (SMP) criterion and the Lemaitre strain equivalence hypothesis, this research develops a constitutive model considering rock chemical corrosion-water-confining pressure damage. The proposed damage constitutive model employs the extremum method to ascertain the two Weibull distribution parameters (m and F(0)) by theoretical derivation and exhibits satisfactory conformity between the theoretical and experimental curves. The damage constitutive model can be consistent in the stress–strain characteristics of the rock triaxial compression process, which verifies the rationality and reliability of the model parameters. The model effectively represents the mechanical properties and damage characteristics of rocks when subjected to the combined influence of water chemistry and confinement. The presented model contributes to a better understanding of tangible rock-engineered structures subjected to chemical corrosion in underwater environments.