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Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis

To reduce the environmental impacts from sodium silicate synthesis, a ceramic method was suggested, with sugarcane bagasse ash (SCBA) as the source of silicon dioxide and sodium carbonate. Although the production of sodium silicate is carried out on a large scale, it should be noted that its process...

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Autores principales: Pérez-Casas, Jesús A., Zaldívar-Cadena, Antonio A., Álvarez-Mendez, Anabel, Ruiz-Valdés, Juan Jacobo, de la Parra-Arciniega, Salomé M., López-Pérez, David C., Sánchez-Vázquez, Astrid I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
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Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10532699/
https://www.ncbi.nlm.nih.gov/pubmed/37763603
http://dx.doi.org/10.3390/ma16186327
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author Pérez-Casas, Jesús A.
Zaldívar-Cadena, Antonio A.
Álvarez-Mendez, Anabel
Ruiz-Valdés, Juan Jacobo
de la Parra-Arciniega, Salomé M.
López-Pérez, David C.
Sánchez-Vázquez, Astrid I.
author_facet Pérez-Casas, Jesús A.
Zaldívar-Cadena, Antonio A.
Álvarez-Mendez, Anabel
Ruiz-Valdés, Juan Jacobo
de la Parra-Arciniega, Salomé M.
López-Pérez, David C.
Sánchez-Vázquez, Astrid I.
author_sort Pérez-Casas, Jesús A.
collection PubMed
description To reduce the environmental impacts from sodium silicate synthesis, a ceramic method was suggested, with sugarcane bagasse ash (SCBA) as the source of silicon dioxide and sodium carbonate. Although the production of sodium silicate is carried out on a large scale, it should be noted that its process requires temperatures above 1000 °C; it also requires the use of highly corrosive agents such as sodium hydroxide and chlorine gas to neutralize the remaining sodium hydroxide. In the present study, the synthesis temperatures were reduced to 800 °C with a reaction time of 3 h by pressing equimolar mixtures of previously purified SCBA and sodium carbonate; then, heat treatment was carried out under the indicated conditions. The resulting materials were analyzed with Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). Among the crystalline phases, calcium disodium silicate was identified, in addition to sodium silicate; thus, it was inferred that the other components of the ash can interfere with the synthesis of silicate. Therefore, in order to obtain the highest composition of sodium silicate, a leaching treatment of the SCBA is required.
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spelling pubmed-105326992023-09-28 Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis Pérez-Casas, Jesús A. Zaldívar-Cadena, Antonio A. Álvarez-Mendez, Anabel Ruiz-Valdés, Juan Jacobo de la Parra-Arciniega, Salomé M. López-Pérez, David C. Sánchez-Vázquez, Astrid I. Materials (Basel) Article To reduce the environmental impacts from sodium silicate synthesis, a ceramic method was suggested, with sugarcane bagasse ash (SCBA) as the source of silicon dioxide and sodium carbonate. Although the production of sodium silicate is carried out on a large scale, it should be noted that its process requires temperatures above 1000 °C; it also requires the use of highly corrosive agents such as sodium hydroxide and chlorine gas to neutralize the remaining sodium hydroxide. In the present study, the synthesis temperatures were reduced to 800 °C with a reaction time of 3 h by pressing equimolar mixtures of previously purified SCBA and sodium carbonate; then, heat treatment was carried out under the indicated conditions. The resulting materials were analyzed with Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). Among the crystalline phases, calcium disodium silicate was identified, in addition to sodium silicate; thus, it was inferred that the other components of the ash can interfere with the synthesis of silicate. Therefore, in order to obtain the highest composition of sodium silicate, a leaching treatment of the SCBA is required. MDPI 2023-09-21 /pmc/articles/PMC10532699/ /pubmed/37763603 http://dx.doi.org/10.3390/ma16186327 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Pérez-Casas, Jesús A.
Zaldívar-Cadena, Antonio A.
Álvarez-Mendez, Anabel
Ruiz-Valdés, Juan Jacobo
de la Parra-Arciniega, Salomé M.
López-Pérez, David C.
Sánchez-Vázquez, Astrid I.
Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis
title Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis
title_full Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis
title_fullStr Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis
title_full_unstemmed Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis
title_short Sugarcane Bagasse Ash as an Alternative Source of Silicon Dioxide in Sodium Silicate Synthesis
title_sort sugarcane bagasse ash as an alternative source of silicon dioxide in sodium silicate synthesis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10532699/
https://www.ncbi.nlm.nih.gov/pubmed/37763603
http://dx.doi.org/10.3390/ma16186327
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