Effect of CrF(3) Addition on Photoluminescence Properties of Lead-Free Cs(4)SnBr(6−x)F(x) Zero-Dimensional Perovskite

Zero-dimensional (0D) tin halide perovskites, characterized by their broadband and adjustable emissions, high photoluminescence quantum yield, and absence of self-absorption, are crucial for the fabrication of high-efficiency optoelectronic devices, such as LEDs, solar cells, and sensors. Despite these attributes, boosting their emission efficiency and stability poses a significant challenge. In this work, Cr(3+)-doped Cs(4)SnBr(6−x)F(x) perovskites were synthesized using a water-assisted wet ball-milling method. The effect of CrF(3) addition on photoluminescence properties of Cs(4)SnBr(6−x)F(x) Perovskites was investigated. We found that Cr(3+)-doped Cs(4)SnBr(6−x)F(x) Perovskites exhibit a broad emission band, a substantial Stokes shift, and an efficient green light emission centered at about 525 nm at ambient temperature. The derived photoluminescence quantum yield amounted to as high as 56.3%. In addition, these Cr(3+)-doped Cs(4)SnBr(6−x)F(x) perovskites outperform their undoped counterparts in terms of thermal stability. Through a comprehensive analysis of photoluminescence measurements, our findings suggested that the elevated photoluminescence quantum yield can be attributed to the enhanced exciton binding energy of self-trapped excitons (STEs) and the suitable electron−phonon coupling resulting from the substantial distortion of [SnBr(6)](4−) octahedra instigated by the addition of CrF(3).