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Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass

The diffusion properties of low-density non-porous silica glasses (expanded silica glasses) were researched with the aim of searching for the molecular structure of membrane materials intended for the effective separation of helium–neon gas mixtures. It has been shown on a large number (84) of compu...

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Detalles Bibliográficos
Autores principales: Kukhtetskiy, Sergey V., Fomenko, Elena V., Anshits, Alexander G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10534533/
https://www.ncbi.nlm.nih.gov/pubmed/37755176
http://dx.doi.org/10.3390/membranes13090754
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author Kukhtetskiy, Sergey V.
Fomenko, Elena V.
Anshits, Alexander G.
author_facet Kukhtetskiy, Sergey V.
Fomenko, Elena V.
Anshits, Alexander G.
author_sort Kukhtetskiy, Sergey V.
collection PubMed
description The diffusion properties of low-density non-porous silica glasses (expanded silica glasses) were researched with the aim of searching for the molecular structure of membrane materials intended for the effective separation of helium–neon gas mixtures. It has been shown on a large number (84) of computer models of such glasses that there are molecular structures of silica in which various helium and neon diffusion mechanisms are simultaneously implemented: superdiffusion for helium and subdiffusion for neon. This makes it possible to significantly (by 3–5 orders of magnitude) increase the helium permeability of such glasses at room temperature and maintain a high selectivity for the separation of helium and neon (at the level of [Formula: see text] – [Formula: see text]) at the same time.
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spelling pubmed-105345332023-09-29 Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass Kukhtetskiy, Sergey V. Fomenko, Elena V. Anshits, Alexander G. Membranes (Basel) Article The diffusion properties of low-density non-porous silica glasses (expanded silica glasses) were researched with the aim of searching for the molecular structure of membrane materials intended for the effective separation of helium–neon gas mixtures. It has been shown on a large number (84) of computer models of such glasses that there are molecular structures of silica in which various helium and neon diffusion mechanisms are simultaneously implemented: superdiffusion for helium and subdiffusion for neon. This makes it possible to significantly (by 3–5 orders of magnitude) increase the helium permeability of such glasses at room temperature and maintain a high selectivity for the separation of helium and neon (at the level of [Formula: see text] – [Formula: see text]) at the same time. MDPI 2023-08-24 /pmc/articles/PMC10534533/ /pubmed/37755176 http://dx.doi.org/10.3390/membranes13090754 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Kukhtetskiy, Sergey V.
Fomenko, Elena V.
Anshits, Alexander G.
Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass
title Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass
title_full Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass
title_fullStr Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass
title_full_unstemmed Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass
title_short Anomalous Diffusion of Helium and Neon in Low-Density Silica Glass
title_sort anomalous diffusion of helium and neon in low-density silica glass
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10534533/
https://www.ncbi.nlm.nih.gov/pubmed/37755176
http://dx.doi.org/10.3390/membranes13090754
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