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Coal Tar Pitch-Based Porous Carbon Loaded MoS(2) and Its Application in Supercapacitors

[Image: see text] In this paper, with coal tar pitch as the carbon source, porous carbon (PC) was prepared by one-step carbonization. To improve the energy density of coal tar pitch-based porous carbon, MoS(2)@PC was prepared by a hydrothermal method on a PC substrate. The effect of MoS(2) loading o...

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Detalles Bibliográficos
Autores principales: Bai, Rui, Cao, Yuan-Jia, Lu, Cui-Ying, Liu, Guang-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10536247/
https://www.ncbi.nlm.nih.gov/pubmed/37779997
http://dx.doi.org/10.1021/acsomega.3c02610
Descripción
Sumario:[Image: see text] In this paper, with coal tar pitch as the carbon source, porous carbon (PC) was prepared by one-step carbonization. To improve the energy density of coal tar pitch-based porous carbon, MoS(2)@PC was prepared by a hydrothermal method on a PC substrate. The effect of MoS(2) loading on the structure and electrochemical properties of the sample was studied. The results show that the specific surface area of the MoS(2)@PC-0.3 synthesized is 3053 m(2) g(–1), and the large specific surface area provides sufficient attachment sites for the storage of electrolyte ions. In the three-electrode system, the specific capacitance of MoS(2)@PC-0.3 at 0.5 A g(–1) is 422.5 F g(–1), and the magnification performance is 57.3% at 20 A g(–1). After 10,000 charge/discharge cycles, the capacitance retention rate of the sample is 76.73%, with the Coulombic efficiency being 100%. In the two-electrode test system, the specific capacitance of MoS(2)@PC-0.3 at 0.5 A g(–1) is 321.4 F g(–1), with the power density and energy density being 500 W kg(–1) and 44.6 Wh kg(–1), respectively. At a current density of 20 A g(–1), the capacitance retention rate is 87.69% after 10,000 cycles. This study greatly improves the energy density of PC as the electrode material of supercapacitors.