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In Situ N, O Co-Doped Nanoporous Carbon Derived from Mixed Egg and Rice Waste as Green Supercapacitor

The conversion of nitrogen–oxygen-rich biomass wastes into heteroatomic co-doped nanostructured carbons used as energy storage materials has received widespread attention. In this study, an in situ nitrogen–oxygen co-doped porous carbon was prepared for supercapacitor applications via a two-step met...

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Detalles Bibliográficos
Autores principales: Qin, Shumeng, Liu, Peiliang, Wang, Jieni, Liu, Chenxiao, Zhang, Shuqin, Tian, Yijun, Zhang, Fangfang, Wang, Lin, Cao, Leichang, Zhang, Jinglai, Zhang, Shicheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10536363/
https://www.ncbi.nlm.nih.gov/pubmed/37764320
http://dx.doi.org/10.3390/molecules28186543
Descripción
Sumario:The conversion of nitrogen–oxygen-rich biomass wastes into heteroatomic co-doped nanostructured carbons used as energy storage materials has received widespread attention. In this study, an in situ nitrogen–oxygen co-doped porous carbon was prepared for supercapacitor applications via a two-step method of pre-carbonization and pyrolytic activation using mixed egg yolk/white and rice waste. The optimal sample (YPAC-1) was found to have a 3D honeycomb structure composed of abundant micropores and mesopores with a high specific surface area of 1572.1 m(2) g(−1), which provided abundant storage space and a wide transport path for electrolyte ions. Notably, the specific capacitance of the constructed three-electrode system was as high as 446.22 F g(−1) at a current density of 1 A g(−1) and remained above 50% at 10 A g(−1). The capacitance retention was 82.26% after up to 10,000 cycles. The symmetrical capacitor based on YPAC-1 with a two-electrode structure exhibited an energy density of 8.3 Wh kg(−1) when the power density was 136 W kg(−1). These results indicate that porous carbon materials prepared from mixed protein and carbohydrate waste have promising applications in the field of supercapacitors.