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Electroplated waveguides to enhance DNP and EPR spectra of silicon and diamond particles

Electroplating the waveguide of a 7 T polarizer in a simple innovative way increased microwave power delivered to the sample by 3.1 dB. Silicon particles, while interesting for hyperpolarized MRI applications, are challenging to polarize due to inefficient microwave multipliers at the electron Larmo...

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Detalles Bibliográficos
Autores principales: Himmler, Aaron, Albannay, Mohammed M., von Witte, Gevin, Kozerke, Sebastian, Ernst, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Copernicus GmbH 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10539804/
https://www.ncbi.nlm.nih.gov/pubmed/37904872
http://dx.doi.org/10.5194/mr-3-203-2022
Descripción
Sumario:Electroplating the waveguide of a 7 T polarizer in a simple innovative way increased microwave power delivered to the sample by 3.1 dB. Silicon particles, while interesting for hyperpolarized MRI applications, are challenging to polarize due to inefficient microwave multipliers at the electron Larmor frequency at high magnetic fields and fast electronic relaxation times. Improving microwave transmission directly translates to more efficient EPR excitation at high-field, low-temperature conditions and promises faster and higher [Formula: see text] Si polarization buildup through dynamic nuclear polarization (DNP).