A Hierarchy of Ligands Controls Formation and Reaction of Aryl Radicals in Pd-Catalyzed Ground-State Base-Promoted Coupling Reactions

[Image: see text] Palladium salts and complexes were tested separately and in the presence of added ligands as potential sources of aryl radicals in ground-state coupling reactions of aryl halide with arenes under basic conditions (KOtBu). Our recently developed assay for aryl radicals was employed...

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Detalles Bibliográficos
Autores principales: Clark, Kenneth F., Tyerman, Seb, Evans, Laura, Robertson, Craig M., Nelson, David J., Kennedy, Alan R., Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10540214/
https://www.ncbi.nlm.nih.gov/pubmed/37713365
http://dx.doi.org/10.1021/jacs.3c05470

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