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Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support

Using two catalysts on a single support can improve reaction efficiency, higher yields, improved selectivity, and simplified reaction conditions, making it a valuable approach for industrial transformation. Herein, we describe the development of a novel and effective heterogeneous catalyst, WCl(6)/C...

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Autores principales: Azizi, Najmedin, Farzaneh, Fezzeh, Farhadi, Elham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10542355/
https://www.ncbi.nlm.nih.gov/pubmed/37777606
http://dx.doi.org/10.1038/s41598-023-43746-y
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author Azizi, Najmedin
Farzaneh, Fezzeh
Farhadi, Elham
author_facet Azizi, Najmedin
Farzaneh, Fezzeh
Farhadi, Elham
author_sort Azizi, Najmedin
collection PubMed
description Using two catalysts on a single support can improve reaction efficiency, higher yields, improved selectivity, and simplified reaction conditions, making it a valuable approach for industrial transformation. Herein, we describe the development of a novel and effective heterogeneous catalyst, WCl(6)/CuCl(2,) supported on graphitic carbon nitride (W/Cu@g-C(3)N(4)), which was synthesized under hydrothermal conditions. The structure and morphology properties of the W/Cu@g-C(3)N(4) were characterized using various spectroscopic techniques, including FTIR, XRD, TEM, TGA, EDX, and SEM. The W/Cu@g-C(3)N(4) support material enabled the rapid and efficient synthesis of benzoxanthenones and xanthenes derivatives in high yields under mild reaction conditions and short reaction times. The W/Cu@g-C(3)N(4) catalyst was also found to be easily recyclable, and its catalytic performance did not significantly decrease after five times use. The findings suggest that W/Cu@g-C(3)N(4) is a promising chemical synthesis catalyst with significant implications for sustainable and cost-effective organic synthesis.
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spelling pubmed-105423552023-10-03 Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support Azizi, Najmedin Farzaneh, Fezzeh Farhadi, Elham Sci Rep Article Using two catalysts on a single support can improve reaction efficiency, higher yields, improved selectivity, and simplified reaction conditions, making it a valuable approach for industrial transformation. Herein, we describe the development of a novel and effective heterogeneous catalyst, WCl(6)/CuCl(2,) supported on graphitic carbon nitride (W/Cu@g-C(3)N(4)), which was synthesized under hydrothermal conditions. The structure and morphology properties of the W/Cu@g-C(3)N(4) were characterized using various spectroscopic techniques, including FTIR, XRD, TEM, TGA, EDX, and SEM. The W/Cu@g-C(3)N(4) support material enabled the rapid and efficient synthesis of benzoxanthenones and xanthenes derivatives in high yields under mild reaction conditions and short reaction times. The W/Cu@g-C(3)N(4) catalyst was also found to be easily recyclable, and its catalytic performance did not significantly decrease after five times use. The findings suggest that W/Cu@g-C(3)N(4) is a promising chemical synthesis catalyst with significant implications for sustainable and cost-effective organic synthesis. Nature Publishing Group UK 2023-09-30 /pmc/articles/PMC10542355/ /pubmed/37777606 http://dx.doi.org/10.1038/s41598-023-43746-y Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Azizi, Najmedin
Farzaneh, Fezzeh
Farhadi, Elham
Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
title Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
title_full Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
title_fullStr Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
title_full_unstemmed Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
title_short Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
title_sort streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10542355/
https://www.ncbi.nlm.nih.gov/pubmed/37777606
http://dx.doi.org/10.1038/s41598-023-43746-y
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