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Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support
Using two catalysts on a single support can improve reaction efficiency, higher yields, improved selectivity, and simplified reaction conditions, making it a valuable approach for industrial transformation. Herein, we describe the development of a novel and effective heterogeneous catalyst, WCl(6)/C...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10542355/ https://www.ncbi.nlm.nih.gov/pubmed/37777606 http://dx.doi.org/10.1038/s41598-023-43746-y |
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author | Azizi, Najmedin Farzaneh, Fezzeh Farhadi, Elham |
author_facet | Azizi, Najmedin Farzaneh, Fezzeh Farhadi, Elham |
author_sort | Azizi, Najmedin |
collection | PubMed |
description | Using two catalysts on a single support can improve reaction efficiency, higher yields, improved selectivity, and simplified reaction conditions, making it a valuable approach for industrial transformation. Herein, we describe the development of a novel and effective heterogeneous catalyst, WCl(6)/CuCl(2,) supported on graphitic carbon nitride (W/Cu@g-C(3)N(4)), which was synthesized under hydrothermal conditions. The structure and morphology properties of the W/Cu@g-C(3)N(4) were characterized using various spectroscopic techniques, including FTIR, XRD, TEM, TGA, EDX, and SEM. The W/Cu@g-C(3)N(4) support material enabled the rapid and efficient synthesis of benzoxanthenones and xanthenes derivatives in high yields under mild reaction conditions and short reaction times. The W/Cu@g-C(3)N(4) catalyst was also found to be easily recyclable, and its catalytic performance did not significantly decrease after five times use. The findings suggest that W/Cu@g-C(3)N(4) is a promising chemical synthesis catalyst with significant implications for sustainable and cost-effective organic synthesis. |
format | Online Article Text |
id | pubmed-10542355 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-105423552023-10-03 Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support Azizi, Najmedin Farzaneh, Fezzeh Farhadi, Elham Sci Rep Article Using two catalysts on a single support can improve reaction efficiency, higher yields, improved selectivity, and simplified reaction conditions, making it a valuable approach for industrial transformation. Herein, we describe the development of a novel and effective heterogeneous catalyst, WCl(6)/CuCl(2,) supported on graphitic carbon nitride (W/Cu@g-C(3)N(4)), which was synthesized under hydrothermal conditions. The structure and morphology properties of the W/Cu@g-C(3)N(4) were characterized using various spectroscopic techniques, including FTIR, XRD, TEM, TGA, EDX, and SEM. The W/Cu@g-C(3)N(4) support material enabled the rapid and efficient synthesis of benzoxanthenones and xanthenes derivatives in high yields under mild reaction conditions and short reaction times. The W/Cu@g-C(3)N(4) catalyst was also found to be easily recyclable, and its catalytic performance did not significantly decrease after five times use. The findings suggest that W/Cu@g-C(3)N(4) is a promising chemical synthesis catalyst with significant implications for sustainable and cost-effective organic synthesis. Nature Publishing Group UK 2023-09-30 /pmc/articles/PMC10542355/ /pubmed/37777606 http://dx.doi.org/10.1038/s41598-023-43746-y Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Azizi, Najmedin Farzaneh, Fezzeh Farhadi, Elham Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support |
title | Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support |
title_full | Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support |
title_fullStr | Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support |
title_full_unstemmed | Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support |
title_short | Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support |
title_sort | streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10542355/ https://www.ncbi.nlm.nih.gov/pubmed/37777606 http://dx.doi.org/10.1038/s41598-023-43746-y |
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