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Unraveling the role of prenyl side-chain interactions in stabilizing the secondary carbocation in the biosynthesis of variexenol B

Terpene cyclization reactions involve a number of carbocation intermediates. In some cases, these carbocations are stabilized by through-space interactions with π orbitals. Several terpene/terpenoids, such as sativene, santalene, bergamotene, ophiobolin and mangicol, possess prenyl side chains that...

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Detalles Bibliográficos
Autores principales: Nakano, Moe, Gemma, Rintaro, Sato, Hajime
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548252/
https://www.ncbi.nlm.nih.gov/pubmed/37799177
http://dx.doi.org/10.3762/bjoc.19.107

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