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Octahedral Zirconium Salan Catalysts for Olefin Polymerization: Substituent and Solvent Effects on Structure and Dynamics
[Image: see text] Group 4 metal-Salan olefin polymerization catalysts typically have relatively low activity, being slowed down by a pre-equilibrium favoring a non-polymerization active resting state identified as a mer-mer isomer (MM); formation of the polymerization active fac-fac species (FF) req...
Autores principales: | Dall’Anese, Anna, Kulyabin, Pavel S., Uborsky, Dmitry V., Vittoria, Antonio, Ehm, Christian, Cipullo, Roberta, Budzelaar, Peter H. M., Voskoboynikov, Alexander Z., Busico, Vincenzo, Tensi, Leonardo, Macchioni, Alceo, Zuccaccia, Cristiano |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548417/ https://www.ncbi.nlm.nih.gov/pubmed/37725565 http://dx.doi.org/10.1021/acs.inorgchem.3c02153 |
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