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–SR removal or –R removal? A mechanistic revisit on the puzzle of ligand etching of Au(25)(SR)(18) nanoclusters during electrocatalysis

Accurate identification of active sites is highly desirable for elucidation of the reaction mechanism and development of efficient catalysts. Despite the promising catalytic performance of thiolated metal nanoclusters (NCs), their actual catalytic sites remain elusive. Traditional first-principles c...

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Detalles Bibliográficos
Autores principales: Sun, Fang, Qin, Lubing, Tang, Zhenghua, Deng, Guocheng, Bootharaju, Megalamane S., Wei, Zidong, Tang, Qing, Hyeon, Taeghwan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548520/
https://www.ncbi.nlm.nih.gov/pubmed/37800008
http://dx.doi.org/10.1039/d3sc03018k

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