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Metal-Mediated Organocatalysis in Water: Serendipitous Discovery of Aldol Reaction Catalyzed by the [Ru(bpy)(2)(nornicotine)(2)](2+) Complex

[Image: see text] The [Ru(bpy)(2)(Nor)(2)](2+) complex (Nor = nornicotine) is an efficient catalyst for the aldol reaction of acetone with activated benzaldehydes in a buffered aqueous solution. The metal plays the role of an activator for the nornicotine organocatalyst ligands. The resulting cataly...

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Detalles Bibliográficos
Autores principales: Guzmán Ríos, David, Romero, Miguel A., González-Delgado, José A., Arteaga, Jesús F., Pischel, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10550203/
https://www.ncbi.nlm.nih.gov/pubmed/35337184
http://dx.doi.org/10.1021/acs.joc.2c00472