Cargando…

Metal-Mediated Organocatalysis in Water: Serendipitous Discovery of Aldol Reaction Catalyzed by the [Ru(bpy)(2)(nornicotine)(2)](2+) Complex

[Image: see text] The [Ru(bpy)(2)(Nor)(2)](2+) complex (Nor = nornicotine) is an efficient catalyst for the aldol reaction of acetone with activated benzaldehydes in a buffered aqueous solution. The metal plays the role of an activator for the nornicotine organocatalyst ligands. The resulting cataly...

Descripción completa

Detalles Bibliográficos
Autores principales:	Guzmán Ríos, David, Romero, Miguel A., González-Delgado, José A., Arteaga, Jesús F., Pischel, Uwe
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10550203/ https://www.ncbi.nlm.nih.gov/pubmed/35337184 http://dx.doi.org/10.1021/acs.joc.2c00472

Ejemplares similares

Surface Enhanced Electrochemiluminescence of Ru(bpy)(3)(2+)
por: Wang, Daifang, et al.
Publicado: (2015)

Excited-State Dynamics of [Ru((S–S)bpy)(bpy)(2)](2+) to Form Long-Lived Localized Triplet States
por: Heindl, Moritz, et al.
Publicado: (2021)

Spectroscopic Studies on Nicotine and Nornicotine in the UV Region†
por: Clayton, Peter M, et al.
Publicado: (2013)

Photocrystallography of [Ru(bpy)(2)(dmso)(2)](2+) reveals an O-bonded metastable state
por: Marr, Zoe Y., et al.
Publicado: (2023)

Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis
por: Gallhof, Malte, et al.
Publicado: (2020)

Serendipitous discoveries in microarray analysis
por: Ellingson, Sally R, et al.
Publicado: (2010)

Recent Developments in the Interactions of Classic Intercalated Ruthenium Compounds: [Ru(bpy)(2)dppz](2+) and [Ru(phen)(2)dppz](2+) with a DNA Molecule
por: Jia, Fuchao, et al.
Publicado: (2019)

Ultrafast in cellulo photoinduced dynamics processes of the paradigm molecular light switch [Ru(bpy)(2)dppz](2+)
por: De la Cadena, Alejandro, et al.
Publicado: (2016)

Trapping intermediate MLCT states in low-symmetry {Ru(bpy)} complexes
por: Cadranel, Alejandro, et al.
Publicado: (2017)

Novel Poly-Dopamine Adhesive for a Halloysite Nanotube-Ru(bpy)(3) (2+) Electrochemiluminescent Sensor
por: Xing, Bo, et al.
Publicado: (2009)

Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media
por: Hatakeda, Miho, et al.
Publicado: (2019)

Walking Along the Serendipitous Path of Discovery
por: Walter, Peter
Publicado: (2010)

Some Other Serendipitous Discoveries in Dermatology
por: Sharma, Yugal K, et al.
Publicado: (2016)

Excited‐State Dynamics of [Ru(bpy)(3)](2+) Thin Films on Sensitized TiO(2) and ZrO(2)
por: Leandri, Valentina, et al.
Publicado: (2019)

An excited state dynamics driven reaction: wavelength-dependent photoisomerization quantum yields in [Ru(bpy)(2)(dmso)(2)](2+)
por: Livshits, Maksim Y., et al.
Publicado: (2020)

Light driven molecular lock comprises a Ru(bpy)(2)(hpip) complex and cucurbit[8]uril
por: Yang, Xiaona, et al.
Publicado: (2021)

Electrogenerated chemiluminescence of a Ru(bpy)(3)(2+)/arginine system: a specific and sensitive detection of acetaminophen
por: Xiao, Yi, et al.
Publicado: (2022)

Crystal structure and redox potentials of the tppz-bridged {RuCl(bpy)}(+) dimer
por: Rein, Francisca N., et al.
Publicado: (2018)

Ratiometric Fluorescence Detection of DNA Based on the Inner Filter Effect of Ru(bpy)(2)(dppx)(2+) toward Silicon Nanodots
por: Zhang, Yanan, et al.
Publicado: (2020)

Evolution of the Serendipitous Discovery of Macrophage–Lymphocyte Interactions
por: Oppenheim, Joost J.
Publicado: (2014)

Quenching Behavior of the Electrochemiluminescence of Ru(bpy)(3) (2+)/TPrA System by Phenols on a Smartphone‐Based Sensor
por: Rivera, Elmer C., et al.
Publicado: (2021)

Silica nanochannels boosting Ru(bpy)(3)(2+)-mediated electrochemical sensor for the detection of guanine in beer and pharmaceutical samples
por: Yang, Luoxing, et al.
Publicado: (2022)

Flexibility and thermal dynamic stability increase of dsDNA induced by Ru(bpy)(2)dppz(2+) based on AFM and HRM technique
por: Jia, Fuchao, et al.
Publicado: (2019)

Organocatalysis
por: List, Benjamin
Publicado: (2012)

Synthesis, characterisation and ion-binding properties of oxathiacrown ethers appended to [Ru(bpy)(2)](2+). Selectivity towards Hg(2+), Cd(2+) and Pb(2+)
por: Odhiambo, Ruth A., et al.
Publicado: (2018)

Serendipitous discovery of Wolbachia genomes in multiple Drosophila species
por: Salzberg, Steven L, et al.
Publicado: (2005)

Serendipitous discovery of phenylketonuria in Iraq – How to identify and treat?
por: Persike de Oliveira, Daniele Suzete, et al.
Publicado: (2021)

Kinetics versus thermodynamics in the proline catalyzed aldol reaction
por: Orlandi, M., et al.
Publicado: (2016)

Noncovalent Interactions in the Oxazaborolidine-Catalyzed Enantioselective Mukaiyama Aldol
por: Farrar, Elliot H. E., et al.
Publicado: (2022)

Visible-Light Actinometry and Intermittent Illumination as Convenient Tools to Study Ru(bpy)(3)Cl(2) Mediated Photoredox Transformations
por: Pitre, Spencer P., et al.
Publicado: (2015)

Crystal structure of a mononuclear Ru(II) complex with a back-to-back terpyridine ligand: [RuCl(bpy)(tpy–tpy)](+)
por: Rein, Francisca N., et al.
Publicado: (2015)

Nicotine alkaloid levels, and nicotine to nornicotine conversion, in Australian Nicotiana species used as chewing tobacco
por: Moghbel, Nahid, et al.
Publicado: (2017)

Anodic Electrogenerated Chemiluminescence of Ru(bpy)(3)(2+) with CdSe Quantum Dots as Coreactant and Its Application in Quantitative Detection of DNA
por: Dong, Yong-Ping, et al.
Publicado: (2015)

[Ru(bpy)(2)(NO)SO(3)](PF(6)), a Nitric Oxide Donating Ruthenium Complex, Reduces Gout Arthritis in Mice
por: Rossaneis, Ana C., et al.
Publicado: (2019)

High Electrochemiluminescence from Ru(bpy)(3) (2+) Embedded Metal–Organic Frameworks to Visualize Single Molecule Movement at the Cellular Membrane
por: Li, Binxiao, et al.
Publicado: (2022)

Correction: Serendipitous discovery of Wolbachia genomes in multiple Drosophila species
por: Salzberg, Steven L, et al.
Publicado: (2005)

Psychopharmacology: From serendipitous discoveries to rationale design, but what next?
por: Robinson, Emma
Publicado: (2018)

In situ remodeling of Montgomery T-tube: Anesthetic challenges and serendipitous discoveries
por: Gupta, Priyanka, et al.
Publicado: (2022)

Crystal structures of three copper(II)–2,2′-bipyridine (bpy) compounds, [Cu(bpy)(2)(H(2)O)][SiF(6)]·4H(2)O, [Cu(bpy)(2)(TaF(6))(2)] and [Cu(bpy)(3)][TaF(6)](2) and a related coordination polymer, [Cu(bpy)(H(2)O)(2)SnF(6)](n)
por: Nisbet, Matthew L., et al.
Publicado: (2021)

Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)(3)(2+) Hybrid Film with Mesoscopic Structures
por: Tsuneyasu, Shota, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_ns505v6io41rdv3i351703f5hn