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Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide
In this study, a tri-component composite named Zr/SiW(12)/GO was meticulously prepared through an ultrasonic-assisted method. This composite incorporates zirconium nanoparticles (Lewis acid), a negatively charged Keggin type polyoxometalate, and graphene oxide, and serves as a remarkable heterogeneo...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10556038/ https://www.ncbi.nlm.nih.gov/pubmed/37798421 http://dx.doi.org/10.1038/s41598-023-43985-z |
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author | Yekke-Ghasemi, Zahra Heravi, Majid M. Malmir, Masoume Mirzaei, Masoud |
author_facet | Yekke-Ghasemi, Zahra Heravi, Majid M. Malmir, Masoume Mirzaei, Masoud |
author_sort | Yekke-Ghasemi, Zahra |
collection | PubMed |
description | In this study, a tri-component composite named Zr/SiW(12)/GO was meticulously prepared through an ultrasonic-assisted method. This composite incorporates zirconium nanoparticles (Lewis acid), a negatively charged Keggin type polyoxometalate, and graphene oxide, and serves as a remarkable heterogeneous catalyst. The Keggin component plays multiple roles as reducing, encapsulating, and bridging agents, resulting in a cooperative effect among the three components that significantly enhances the catalytic activity. The catalytic performance of Zr/SiW(12)/GO was thoroughly investigated in the oxidation of sulfides to sulfoxides under mild conditions, employing H(2)O(2) as the oxidant. Remarkably, this composite exhibited exceptional stability and could be effortlessly recovered and reused up to four times without any noticeable loss in its catalytic activity. |
format | Online Article Text |
id | pubmed-10556038 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-105560382023-10-07 Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide Yekke-Ghasemi, Zahra Heravi, Majid M. Malmir, Masoume Mirzaei, Masoud Sci Rep Article In this study, a tri-component composite named Zr/SiW(12)/GO was meticulously prepared through an ultrasonic-assisted method. This composite incorporates zirconium nanoparticles (Lewis acid), a negatively charged Keggin type polyoxometalate, and graphene oxide, and serves as a remarkable heterogeneous catalyst. The Keggin component plays multiple roles as reducing, encapsulating, and bridging agents, resulting in a cooperative effect among the three components that significantly enhances the catalytic activity. The catalytic performance of Zr/SiW(12)/GO was thoroughly investigated in the oxidation of sulfides to sulfoxides under mild conditions, employing H(2)O(2) as the oxidant. Remarkably, this composite exhibited exceptional stability and could be effortlessly recovered and reused up to four times without any noticeable loss in its catalytic activity. Nature Publishing Group UK 2023-10-05 /pmc/articles/PMC10556038/ /pubmed/37798421 http://dx.doi.org/10.1038/s41598-023-43985-z Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Yekke-Ghasemi, Zahra Heravi, Majid M. Malmir, Masoume Mirzaei, Masoud Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide |
title | Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide |
title_full | Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide |
title_fullStr | Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide |
title_full_unstemmed | Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide |
title_short | Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide |
title_sort | efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous zr-containing polyoxometalate grafted on graphene oxide |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10556038/ https://www.ncbi.nlm.nih.gov/pubmed/37798421 http://dx.doi.org/10.1038/s41598-023-43985-z |
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