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Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture

[Image: see text] We identify the factors that rule the selectivity in single-cleavage skeletal rearrangements promoted by gold(I) catalysts. We find that stereoconvergence is enabled by a rotational equilibrium when electron-rich substituents are used. The anomalous Z-selective skeletal rearrangeme...

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Detalles Bibliográficos
Autores principales:	García-Padilla, Eduardo, Maseras, Feliu, Echavarren, Antonio M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10557124/ https://www.ncbi.nlm.nih.gov/pubmed/37810414 http://dx.doi.org/10.1021/acsorginorgau.3c00028

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