Cryo-annealing of Photoreduced CdS Quantum Dot–Nitrogenase MoFe Protein Complexes Reveals the Kinetic Stability of the E(4)(2N2H) Intermediate

[Image: see text] A critical step in the mechanism of N(2) reduction to 2NH(3) catalyzed by the enzyme nitrogenase is the reaction of the four-electron/four-proton reduced intermediate state of the active-site FeMo-cofactor (E(4)(4H)). This state is a junction in the catalytic mechanism, either rela...

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Detalles Bibliográficos
Autores principales: Vansuch, Gregory E., Mulder, David W., Chica, Bryant, Ruzicka, Jesse L., Yang, Zhi-Yong, Pellows, Lauren M., Willis, Mark A., Brown, Katherine A., Seefeldt, Lance C., Peters, John W., Dukovic, Gordana, King, Paul W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10557137/
https://www.ncbi.nlm.nih.gov/pubmed/37729189
http://dx.doi.org/10.1021/jacs.3c06832

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