Variations on the Bergman Cyclization Theme: Electrocyclizations of Ionic Penta-, Hepta-, and Octadiynes

[Image: see text] The Bergman cyclization of (Z)-hexa-3-ene-1,5-diyne to form the aromatic diradical p-benzyne has garnered attention as a potential antitumor agent due to its relatively low cyclization barrier and the stability of the resulting diradical. Here, we present a theoretical investigatio...

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Detalles Bibliográficos
Autores principales: Sirianni, Dominic A., Song, Xinli, Wairegi, Salmika, Wang, Evan B., Mendoza-Gomez, Sebastian A., Luxon, Adam, Zimmerley, Maxwell, Nussdorf, Ariana, Filatov, Michael, Hoffmann, Roald, Parish, Carol A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10557144/
https://www.ncbi.nlm.nih.gov/pubmed/37747784
http://dx.doi.org/10.1021/jacs.3c06691

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