Evidence of electronic influence in the adsorption of cationic and zwitterionic dyes on zeolites

The adsorption of a cationic dye, Methylene blue (MB), and a zwitterionic dye, 8-Hydroxyquinoline (8-HQ), onto zeolites synthesized from different clays has been investigated. The presence of certain metals and the Si/Al ratio of the parent clay has an overall effect on the type of zeolites produced. Zeolites LTA and FAU Y were obtained using the hydrothermal method. X-ray diffraction and Fourier transform infrared spectroscopy (FTIR) spectral analysis was used to study the adsorption phenomena of the adsorbates on the adsorbents. The adsorption profile of MB (Topological Polar Surface Area (TPSA) 43.9 Å(2) and 8-HQ (TPSA 33.1 Å(2)) compared favourably with a Freundlich isotherm with R(2) > 0.9 for all the zeolitic materials synthesized. Adsorption capacities of zeolite FAU was significantly different from zeolite LTA for MB removal. The higher adsorption capacity of zeolite FAU was attributed to geometric effects resulting in greater shrinkage in the inter lattice spacing of zeolite LTA leading to a reduction in surface area. Adsorption of the relatively smaller 8-HQ however, did not show significant difference in the two zeolite types. Surface and structural characterization showed that adsorbates/adsorbents interactions were driven by both geometric (inter lattice spacing which imparts higher surface area of the adsorbent) and electronic (electrostatic repulsions through electron back donation from metals in the zeolitic structure) considerations.