Synthesis, crystal structure and thermal behavior of tetra­kis­(3-cyano­pyridine N-oxide-κO)bis­(thio­cyanato-κN)cobalt(II), which shows strong pseudo­symmetry

The title compound, [Co(SCN)(2)(C(6)H(4)N(2)O)(4)], was prepared by the reaction of cobalt(II)thio­cyanate with 3-cyano­pyridine N-oxide in ethanol. In the crystal, the cobalt(II) cations are octa­hedrally coordinated by two terminal N-bonded thio­cyanate anions and four O-bonded 3-cyano­pyridine N-oxide coligands, forming discrete complexes that are located on centers of inversion, hence forming trans-CoN(2)O(4) octa­hedra. The structure refinement was performed in the monoclinic space group P2(1)/n, for which a potential lattice translation and new symmetry elements with a fit of 100% is suggested. The structure can easily be refined in the space group I2/m, where the complexes have 2/m symmetry. However, nearly all of the reflections that violate the centering are observed with significant intensity and the refinement in P2(1)/n leads to significantly lower R(F) values (0.027 versus 0.033). Moreover, in I2/m much larger components of the anisotropic displacement parameters are observed and therefore, the crystal structure is presented in the primitive unit cell. IR investigations confirm that the anionic ligands are only terminally bonded and that the cyano group is not involved in the metal coordination. PXRD investigations show that a pure crystalline phase has been obtained and measurements using simultaneously thermogravimetry and differential thermoanalysis reveal that the compound decomposes in an exothermic reaction upon heating, without the formation of a coligand-deficient inter­mediate phase.