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Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2) N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2) O:O (2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology
The title compound, {[Zn(C(10)H(6)O(4))(C(16)H(16)N(4)O(2)]·2.5H(2)O}( n ), contains five-coordinate Zn(II) ions intermediate between square-pyramidal and trigonal–bipyramidal coordination environments. The Zn(II) ions are connected by 2-carboxycinnamate (cca) ligands and N,N′-bis-(pyridine-4-car...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561219/ https://www.ncbi.nlm.nih.gov/pubmed/37818466 http://dx.doi.org/10.1107/S2414314623008118 |
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| author | Glatz, Erika J. LaDuca, Robert L. |
| author_facet | Glatz, Erika J. LaDuca, Robert L. |
| author_sort | Glatz, Erika J. |
| collection | PubMed |
| description | The title compound, {[Zn(C(10)H(6)O(4))(C(16)H(16)N(4)O(2)]·2.5H(2)O}( n ), contains five-coordinate Zn(II) ions intermediate between square-pyramidal and trigonal–bipyramidal coordination environments. The Zn(II) ions are connected by 2-carboxycinnamate (cca) ligands and N,N′-bis-(pyridine-4-carboxamido)piperazine (4-pcap) ligands to construct a non-interpenetrated, tri-periodic coordination polymer with embedded [Zn(2)(OCO)(2)] dimeric units. Treating these as six-connected nodes reveals an overall (4(12)6(3)) pcu topology. One of the 4-pcap piperazinyl rings is disordered equally over two sets of crystallographic positions. [Image: see text] |
| format | Online Article Text |
| id | pubmed-10561219 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-105612192023-10-10 Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2) N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2) O:O (2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology Glatz, Erika J. LaDuca, Robert L. IUCrdata Data Reports The title compound, {[Zn(C(10)H(6)O(4))(C(16)H(16)N(4)O(2)]·2.5H(2)O}( n ), contains five-coordinate Zn(II) ions intermediate between square-pyramidal and trigonal–bipyramidal coordination environments. The Zn(II) ions are connected by 2-carboxycinnamate (cca) ligands and N,N′-bis-(pyridine-4-carboxamido)piperazine (4-pcap) ligands to construct a non-interpenetrated, tri-periodic coordination polymer with embedded [Zn(2)(OCO)(2)] dimeric units. Treating these as six-connected nodes reveals an overall (4(12)6(3)) pcu topology. One of the 4-pcap piperazinyl rings is disordered equally over two sets of crystallographic positions. [Image: see text] International Union of Crystallography 2023-09-22 /pmc/articles/PMC10561219/ /pubmed/37818466 http://dx.doi.org/10.1107/S2414314623008118 Text en © Glatz and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Glatz, Erika J. LaDuca, Robert L. Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2) N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2) O:O (2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology |
| title | Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2)
N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2)
O:O
(2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology |
| title_full | Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2)
N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2)
O:O
(2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology |
| title_fullStr | Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2)
N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2)
O:O
(2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology |
| title_full_unstemmed | Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2)
N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2)
O:O
(2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology |
| title_short | Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2)
N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2)
O:O
(2)]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology |
| title_sort | poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ(2)
n:n′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ(2)
o:o
(2)]zinc(ii)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561219/ https://www.ncbi.nlm.nih.gov/pubmed/37818466 http://dx.doi.org/10.1107/S2414314623008118 |
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