Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]

The title compound, [Ni(C(10)H(8)O(4))(C(16)H(20)N(4))(H(2)O)(2)]( n ), contains Ni(II) cations octa­hedrally surrounded within an [O(4)N(2)] coordination set. The cations are linked by 4-(carb­oxy­eth­yl)benzoate (ceb) and 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (bpmp) ligands into tri-periodic dia...

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Detalles Bibliográficos
Autores principales: Gaskin, Gabrielle J., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561224/
https://www.ncbi.nlm.nih.gov/pubmed/37818471
http://dx.doi.org/10.1107/S2414314623007885
Descripción
Sumario:The title compound, [Ni(C(10)H(8)O(4))(C(16)H(20)N(4))(H(2)O)(2)]( n ), contains Ni(II) cations octa­hedrally surrounded within an [O(4)N(2)] coordination set. The cations are linked by 4-(carb­oxy­eth­yl)benzoate (ceb) and 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (bpmp) ligands into tri-periodic diamondoid (dia) networks. The fivefold inter­penetrated dia networks are held into the crystal structure by means of O—H⋯O hydrogen bonding between bound water mol­ecules and unligated carboxyl­ate O atoms of the ceb ligands. [Image: see text]

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