Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]

The title compound, [Ni(C(10)H(8)O(4))(C(16)H(20)N(4))(H(2)O)(2)]( n ), contains Ni(II) cations octa­hedrally surrounded within an [O(4)N(2)] coordination set. The cations are linked by 4-(carb­oxy­eth­yl)benzoate (ceb) and 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (bpmp) ligands into tri-periodic dia...

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Detalles Bibliográficos
Autores principales: Gaskin, Gabrielle J., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561224/
https://www.ncbi.nlm.nih.gov/pubmed/37818471
http://dx.doi.org/10.1107/S2414314623007885
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author Gaskin, Gabrielle J.
LaDuca, Robert L.
author_facet Gaskin, Gabrielle J.
LaDuca, Robert L.
author_sort Gaskin, Gabrielle J.
collection PubMed
description The title compound, [Ni(C(10)H(8)O(4))(C(16)H(20)N(4))(H(2)O)(2)]( n ), contains Ni(II) cations octa­hedrally surrounded within an [O(4)N(2)] coordination set. The cations are linked by 4-(carb­oxy­eth­yl)benzoate (ceb) and 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (bpmp) ligands into tri-periodic diamondoid (dia) networks. The fivefold inter­penetrated dia networks are held into the crystal structure by means of O—H⋯O hydrogen bonding between bound water mol­ecules and unligated carboxyl­ate O atoms of the ceb ligands. [Image: see text]
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spelling pubmed-105612242023-10-10 Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)] Gaskin, Gabrielle J. LaDuca, Robert L. IUCrdata Data Reports The title compound, [Ni(C(10)H(8)O(4))(C(16)H(20)N(4))(H(2)O)(2)]( n ), contains Ni(II) cations octa­hedrally surrounded within an [O(4)N(2)] coordination set. The cations are linked by 4-(carb­oxy­eth­yl)benzoate (ceb) and 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (bpmp) ligands into tri-periodic diamondoid (dia) networks. The fivefold inter­penetrated dia networks are held into the crystal structure by means of O—H⋯O hydrogen bonding between bound water mol­ecules and unligated carboxyl­ate O atoms of the ceb ligands. [Image: see text] International Union of Crystallography 2023-09-22 /pmc/articles/PMC10561224/ /pubmed/37818471 http://dx.doi.org/10.1107/S2414314623007885 Text en © Gaskin and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Gaskin, Gabrielle J.
LaDuca, Robert L.
Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]
title Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]
title_full Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]
title_fullStr Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]
title_full_unstemmed Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]
title_short Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]
title_sort poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561224/
https://www.ncbi.nlm.nih.gov/pubmed/37818471
http://dx.doi.org/10.1107/S2414314623007885
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