N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate

The title compound, C(26)H(26)N(4)O(6)·2C(4)H(8)O, representing a bis-urea with terminal phenyl­alanine units, crystallized with two tetra­hydro­furan (THF) mol­ecules. The main mol­ecule is located on a crystallographic twofold axis, while the solvent mol­ecule is disordered over two positions, wit...

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Detalles Bibliográficos
Autores principales: Stapf, Manuel, Schwarzer, Anke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561225/
https://www.ncbi.nlm.nih.gov/pubmed/37818468
http://dx.doi.org/10.1107/S2414314623007435
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author Stapf, Manuel
Schwarzer, Anke
author_facet Stapf, Manuel
Schwarzer, Anke
author_sort Stapf, Manuel
collection PubMed
description The title compound, C(26)H(26)N(4)O(6)·2C(4)H(8)O, representing a bis-urea with terminal phenyl­alanine units, crystallized with two tetra­hydro­furan (THF) mol­ecules. The main mol­ecule is located on a crystallographic twofold axis, while the solvent mol­ecule is disordered over two positions, with occupancies of 0.571 (15) and 0.429 (15). The host mol­ecules are linked by N—H⋯O=C hydrogen bonds and C—H⋯O contacts with R (2) (1)(6) and R (2) (1)(7) ring motifs. The THF mol­ecules enclosed in the crystal are connected to the bis-urea compound via O—H⋯O and C—H⋯O inter­actions. [Image: see text]
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spelling pubmed-105612252023-10-10 N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate Stapf, Manuel Schwarzer, Anke IUCrdata Data Reports The title compound, C(26)H(26)N(4)O(6)·2C(4)H(8)O, representing a bis-urea with terminal phenyl­alanine units, crystallized with two tetra­hydro­furan (THF) mol­ecules. The main mol­ecule is located on a crystallographic twofold axis, while the solvent mol­ecule is disordered over two positions, with occupancies of 0.571 (15) and 0.429 (15). The host mol­ecules are linked by N—H⋯O=C hydrogen bonds and C—H⋯O contacts with R (2) (1)(6) and R (2) (1)(7) ring motifs. The THF mol­ecules enclosed in the crystal are connected to the bis-urea compound via O—H⋯O and C—H⋯O inter­actions. [Image: see text] International Union of Crystallography 2023-09-08 /pmc/articles/PMC10561225/ /pubmed/37818468 http://dx.doi.org/10.1107/S2414314623007435 Text en © Stapf and Schwarzer 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Stapf, Manuel
Schwarzer, Anke
N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate
title N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate
title_full N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate
title_fullStr N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate
title_full_unstemmed N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate
title_short N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate
title_sort n,n′-[1,4-phenyl­enebis(imino­carbon­yl)]bis­(l-phenyl­alanine) tetra­hydro­furan disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561225/
https://www.ncbi.nlm.nih.gov/pubmed/37818468
http://dx.doi.org/10.1107/S2414314623007435
work_keys_str_mv AT stapfmanuel nn14phenylenebisiminocarbonylbislphenylalaninetetrahydrofurandisolvate
AT schwarzeranke nn14phenylenebisiminocarbonylbislphenylalaninetetrahydrofurandisolvate

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