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Poly[[μ-1,3-bis(pyridin-3-yl)urea]bis(μ(4)-glutarato)dicopper(II)]
The title compound, [Cu(2)(C(5)H(6)O(4))(2)(C(11)H(10)N(4)O)]( n ), contains square-pyramidally coordinated Cu(II) ions linked by anti-gauche conformation glutarate (glu) ligands into [Cu(2)(glu)(2)]( n ) di-periodic coordination polymer layers with embedded [Cu(2)(OCO)(4)] paddlewheel clusters. In...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561227/ https://www.ncbi.nlm.nih.gov/pubmed/37818463 http://dx.doi.org/10.1107/S2414314623008337 |
Sumario: | The title compound, [Cu(2)(C(5)H(6)O(4))(2)(C(11)H(10)N(4)O)]( n ), contains square-pyramidally coordinated Cu(II) ions linked by anti-gauche conformation glutarate (glu) ligands into [Cu(2)(glu)(2)]( n ) di-periodic coordination polymer layers with embedded [Cu(2)(OCO)(4)] paddlewheel clusters. In turn, the layer motifs are connected by 1,3-di(pyridin-3-yl)urea (3-dpu) linkers to form a [Cu(2)(glu)(2)(3-dpu)]( n ) tri-periodic coordination polymer network. Treating the [Cu(2)(OCO)(4)] clusters as 6-connected nodes reveals an underlying 4(12)6(3) pcu topology according to TOPOSPRO software [Blatov et al. (2014 ▸). Cryst. Growth Des. 14, 3576–3586]. [Image: see text] |
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