Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)]

The title compound, [Cu(2)(C(5)H(6)O(4))(2)(C(11)H(10)N(4)O)]( n ), contains square-pyramidally coordinated Cu(II) ions linked by anti-gauche conformation glutarate (glu) ligands into [Cu(2)(glu)(2)]( n ) di-periodic coordination polymer layers with embedded [Cu(2)(OCO)(4)] paddlewheel clusters. In...

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Detalles Bibliográficos
Autores principales: Ezenyilimba, Frederick C., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561227/
https://www.ncbi.nlm.nih.gov/pubmed/37818463
http://dx.doi.org/10.1107/S2414314623008337
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author Ezenyilimba, Frederick C.
LaDuca, Robert L.
author_facet Ezenyilimba, Frederick C.
LaDuca, Robert L.
author_sort Ezenyilimba, Frederick C.
collection PubMed
description The title compound, [Cu(2)(C(5)H(6)O(4))(2)(C(11)H(10)N(4)O)]( n ), contains square-pyramidally coordinated Cu(II) ions linked by anti-gauche conformation glutarate (glu) ligands into [Cu(2)(glu)(2)]( n ) di-periodic coordination polymer layers with embedded [Cu(2)(OCO)(4)] paddlewheel clusters. In turn, the layer motifs are connected by 1,3-di(pyridin-3-yl)urea (3-dpu) linkers to form a [Cu(2)(glu)(2)(3-dpu)]( n ) tri-periodic coordination polymer network. Treating the [Cu(2)(OCO)(4)] clusters as 6-connected nodes reveals an underlying 4(12)6(3) pcu topology according to TOPOSPRO software [Blatov et al. (2014 ▸). Cryst. Growth Des. 14, 3576–3586]. [Image: see text]
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spelling pubmed-105612272023-10-10 Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)] Ezenyilimba, Frederick C. LaDuca, Robert L. IUCrdata Data Reports The title compound, [Cu(2)(C(5)H(6)O(4))(2)(C(11)H(10)N(4)O)]( n ), contains square-pyramidally coordinated Cu(II) ions linked by anti-gauche conformation glutarate (glu) ligands into [Cu(2)(glu)(2)]( n ) di-periodic coordination polymer layers with embedded [Cu(2)(OCO)(4)] paddlewheel clusters. In turn, the layer motifs are connected by 1,3-di(pyridin-3-yl)urea (3-dpu) linkers to form a [Cu(2)(glu)(2)(3-dpu)]( n ) tri-periodic coordination polymer network. Treating the [Cu(2)(OCO)(4)] clusters as 6-connected nodes reveals an underlying 4(12)6(3) pcu topology according to TOPOSPRO software [Blatov et al. (2014 ▸). Cryst. Growth Des. 14, 3576–3586]. [Image: see text] International Union of Crystallography 2023-09-26 /pmc/articles/PMC10561227/ /pubmed/37818463 http://dx.doi.org/10.1107/S2414314623008337 Text en © Ezenyilimba and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ezenyilimba, Frederick C.
LaDuca, Robert L.
Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)]
title Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)]
title_full Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)]
title_fullStr Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)]
title_full_unstemmed Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)]
title_short Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(II)]
title_sort poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ(4)-glutarato)dicopper(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561227/
https://www.ncbi.nlm.nih.gov/pubmed/37818463
http://dx.doi.org/10.1107/S2414314623008337
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