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catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]

The title compound, {[Cu(C(10)H(7)O(4))(2)(C(14)H(14)N(4)O(2))(H(2)O)(2)]( n ), contains octa­hed­rally coordinated Cu(II) ions ligated by two bis­(1,3-di­hydro-3-oxo-1-isobenzo­furan­acetate (dibf) ligands and two trans water mol­ecules, linked by N,N′-(ethane-1,2-di­yl)dinicotinamide (edn) ligands...

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Detalles Bibliográficos
Autores principales: Pumford, Sean R., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561234/
https://www.ncbi.nlm.nih.gov/pubmed/37818477
http://dx.doi.org/10.1107/S2414314623007642
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author Pumford, Sean R.
LaDuca, Robert L.
author_facet Pumford, Sean R.
LaDuca, Robert L.
author_sort Pumford, Sean R.
collection PubMed
description The title compound, {[Cu(C(10)H(7)O(4))(2)(C(14)H(14)N(4)O(2))(H(2)O)(2)]( n ), contains octa­hed­rally coordinated Cu(II) ions ligated by two bis­(1,3-di­hydro-3-oxo-1-isobenzo­furan­acetate (dibf) ligands and two trans water mol­ecules, linked by N,N′-(ethane-1,2-di­yl)dinicotinamide (edn) ligands into mono-periodic coordination polymer chains. The dibf ligands exhibit a pseudo-mirror positional disorder over two positions in a 89.2 (3)/10.8 (3) ratio; the central amide groups of the edn ligands are disordered pseudo-rotationally in the same ratio. These mono-periodic chain motifs are held into supra­molecular di-periodic supra­molecular layers by means of N—H⋯O hydrogen bonding between edn amide groups and unligated dibf carboxyl­ate O atoms. In turn, the supra­molecular layers are held by crystal packing forces into the full crystal structure of the title compound. [Image: see text]
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spelling pubmed-105612342023-10-10 catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide] Pumford, Sean R. LaDuca, Robert L. IUCrdata Data Reports The title compound, {[Cu(C(10)H(7)O(4))(2)(C(14)H(14)N(4)O(2))(H(2)O)(2)]( n ), contains octa­hed­rally coordinated Cu(II) ions ligated by two bis­(1,3-di­hydro-3-oxo-1-isobenzo­furan­acetate (dibf) ligands and two trans water mol­ecules, linked by N,N′-(ethane-1,2-di­yl)dinicotinamide (edn) ligands into mono-periodic coordination polymer chains. The dibf ligands exhibit a pseudo-mirror positional disorder over two positions in a 89.2 (3)/10.8 (3) ratio; the central amide groups of the edn ligands are disordered pseudo-rotationally in the same ratio. These mono-periodic chain motifs are held into supra­molecular di-periodic supra­molecular layers by means of N—H⋯O hydrogen bonding between edn amide groups and unligated dibf carboxyl­ate O atoms. In turn, the supra­molecular layers are held by crystal packing forces into the full crystal structure of the title compound. [Image: see text] International Union of Crystallography 2023-09-08 /pmc/articles/PMC10561234/ /pubmed/37818477 http://dx.doi.org/10.1107/S2414314623007642 Text en © Pumford and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Pumford, Sean R.
LaDuca, Robert L.
catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]
title catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]
title_full catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]
title_fullStr catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]
title_full_unstemmed catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]
title_short catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]
title_sort catena-poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(ii)]-μ-n,n′-(ethane-1,2-di­yl)dinicotinamide]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561234/
https://www.ncbi.nlm.nih.gov/pubmed/37818477
http://dx.doi.org/10.1107/S2414314623007642
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