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catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide]
The title compound, {[Cu(C(10)H(7)O(4))(2)(C(14)H(14)N(4)O(2))(H(2)O)(2)]( n ), contains octahedrally coordinated Cu(II) ions ligated by two bis(1,3-dihydro-3-oxo-1-isobenzofuranacetate (dibf) ligands and two trans water molecules, linked by N,N′-(ethane-1,2-diyl)dinicotinamide (edn) ligands...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561234/ https://www.ncbi.nlm.nih.gov/pubmed/37818477 http://dx.doi.org/10.1107/S2414314623007642 |
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author | Pumford, Sean R. LaDuca, Robert L. |
author_facet | Pumford, Sean R. LaDuca, Robert L. |
author_sort | Pumford, Sean R. |
collection | PubMed |
description | The title compound, {[Cu(C(10)H(7)O(4))(2)(C(14)H(14)N(4)O(2))(H(2)O)(2)]( n ), contains octahedrally coordinated Cu(II) ions ligated by two bis(1,3-dihydro-3-oxo-1-isobenzofuranacetate (dibf) ligands and two trans water molecules, linked by N,N′-(ethane-1,2-diyl)dinicotinamide (edn) ligands into mono-periodic coordination polymer chains. The dibf ligands exhibit a pseudo-mirror positional disorder over two positions in a 89.2 (3)/10.8 (3) ratio; the central amide groups of the edn ligands are disordered pseudo-rotationally in the same ratio. These mono-periodic chain motifs are held into supramolecular di-periodic supramolecular layers by means of N—H⋯O hydrogen bonding between edn amide groups and unligated dibf carboxylate O atoms. In turn, the supramolecular layers are held by crystal packing forces into the full crystal structure of the title compound. [Image: see text] |
format | Online Article Text |
id | pubmed-10561234 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-105612342023-10-10 catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide] Pumford, Sean R. LaDuca, Robert L. IUCrdata Data Reports The title compound, {[Cu(C(10)H(7)O(4))(2)(C(14)H(14)N(4)O(2))(H(2)O)(2)]( n ), contains octahedrally coordinated Cu(II) ions ligated by two bis(1,3-dihydro-3-oxo-1-isobenzofuranacetate (dibf) ligands and two trans water molecules, linked by N,N′-(ethane-1,2-diyl)dinicotinamide (edn) ligands into mono-periodic coordination polymer chains. The dibf ligands exhibit a pseudo-mirror positional disorder over two positions in a 89.2 (3)/10.8 (3) ratio; the central amide groups of the edn ligands are disordered pseudo-rotationally in the same ratio. These mono-periodic chain motifs are held into supramolecular di-periodic supramolecular layers by means of N—H⋯O hydrogen bonding between edn amide groups and unligated dibf carboxylate O atoms. In turn, the supramolecular layers are held by crystal packing forces into the full crystal structure of the title compound. [Image: see text] International Union of Crystallography 2023-09-08 /pmc/articles/PMC10561234/ /pubmed/37818477 http://dx.doi.org/10.1107/S2414314623007642 Text en © Pumford and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Pumford, Sean R. LaDuca, Robert L. catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide] |
title |
catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide] |
title_full |
catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide] |
title_fullStr |
catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide] |
title_full_unstemmed |
catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide] |
title_short |
catena-Poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(II)]-μ-N,N′-(ethane-1,2-diyl)dinicotinamide] |
title_sort | catena-poly[[diaquabis(1,3-dihydro-3-oxoisobenzofuran-1-acetato)copper(ii)]-μ-n,n′-(ethane-1,2-diyl)dinicotinamide] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10561234/ https://www.ncbi.nlm.nih.gov/pubmed/37818477 http://dx.doi.org/10.1107/S2414314623007642 |
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