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Catalytic atroposelective synthesis of heterobiaryls with vicinal C−C and N−N diaxes via dynamic kinetic resolution

Reported herein is a highly efficient dynamic kinetic resolution protocol for the atroposelective synthesis of heterobiaryls with vicinal C−C and N−N diaxes. Atropisomers bearing vicinal diaxes mainly exist in o-triaryls, while that of biaryls is highly challenging in terms of the concerted rotation...

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Detalles Bibliográficos
Autores principales:	Han, Tian-Jiao, Guan, Chun-Yan, Li, Na, Dong, Rui, Xu, Li-Ping, Xiao, Xiao, Wang, Min-Can, Mei, Guang-Jian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Elsevier 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10562788/ https://www.ncbi.nlm.nih.gov/pubmed/37822512 http://dx.doi.org/10.1016/j.isci.2023.107978

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