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Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex

Despite the myriad Cu-catalyzed nitrene transfer methodologies to form new C–N bonds (e.g., amination, aziridination), the critical reaction intermediates have largely eluded direct characterization due to their inherent reactivity. Herein, we report the synthesis of dipyrrin-supported Cu nitrenoid...

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Detalles Bibliográficos
Autores principales: Carsch, Kurtis M., North, Sasha C., DiMucci, Ida M., Iliescu, Andrei, Vojáčková, Petra, Khazanov, Thomas, Zheng, Shao-Liang, Cundari, Thomas R., Lancaster, Kyle M., Betley, Theodore A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10566472/
https://www.ncbi.nlm.nih.gov/pubmed/37829016
http://dx.doi.org/10.1039/d3sc03641c

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