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Competing quantum effects in heavy-atom tunnelling through conical intersections
Thermally activated chemical reactions are typically understood in terms of overcoming potential-energy barriers. However, standard rate theories break down in the presence of a conical intersection (CI) because these processes are inherently nonadiabatic, invalidating the Born–Oppenheimer approxima...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10566476/ https://www.ncbi.nlm.nih.gov/pubmed/37829019 http://dx.doi.org/10.1039/d3sc03706a |