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Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas

[Image: see text] Nowadays, the Claus process is one of the most efficient procedures to recover sulfur from acid gases. In the current study, the effect of working pressure and the role of initial species (sour gas, ammonia, carbon dioxide, hydrocarbon, nitrogen, and oxygen) are analyzed using COMS...

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Autores principales: Eskandarzadeh, Hossein, Akbari, Ghasem, Yazdi, Mohammad Eftekhari, Lohrasbi Nichkoohi, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10568715/
https://www.ncbi.nlm.nih.gov/pubmed/37841124
http://dx.doi.org/10.1021/acsomega.3c03065
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author Eskandarzadeh, Hossein
Akbari, Ghasem
Yazdi, Mohammad Eftekhari
Lohrasbi Nichkoohi, Ali
author_facet Eskandarzadeh, Hossein
Akbari, Ghasem
Yazdi, Mohammad Eftekhari
Lohrasbi Nichkoohi, Ali
author_sort Eskandarzadeh, Hossein
collection PubMed
description [Image: see text] Nowadays, the Claus process is one of the most efficient procedures to recover sulfur from acid gases. In the current study, the effect of working pressure and the role of initial species (sour gas, ammonia, carbon dioxide, hydrocarbon, nitrogen, and oxygen) are analyzed using COMSOL software. The reaction occurs between acid gases, which contain 88% H(2)S, 10.5% CO(2), 0.49% N(2), and 1.01% CH(4) in terms of molar percentage, and pure air. A good agreement is obtained between the numerical simulation results and experimental data. According to the results, there is a direct correlation between the conversion rate of acid gases and the increase in pressure. However, this rise in reactor pressure also leads to an undesirable increase in the outlet temperature. It is also observed that reduction of hydrogen sulfide inflow decreases the sulfur monoxide production rate, which in turn significantly affects the reactor temperature and the sulfur recovery rate. The more the oxygen that enters the reactor, the more the hydrogen sulfides that change into sulfur.
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spelling pubmed-105687152023-10-13 Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas Eskandarzadeh, Hossein Akbari, Ghasem Yazdi, Mohammad Eftekhari Lohrasbi Nichkoohi, Ali ACS Omega [Image: see text] Nowadays, the Claus process is one of the most efficient procedures to recover sulfur from acid gases. In the current study, the effect of working pressure and the role of initial species (sour gas, ammonia, carbon dioxide, hydrocarbon, nitrogen, and oxygen) are analyzed using COMSOL software. The reaction occurs between acid gases, which contain 88% H(2)S, 10.5% CO(2), 0.49% N(2), and 1.01% CH(4) in terms of molar percentage, and pure air. A good agreement is obtained between the numerical simulation results and experimental data. According to the results, there is a direct correlation between the conversion rate of acid gases and the increase in pressure. However, this rise in reactor pressure also leads to an undesirable increase in the outlet temperature. It is also observed that reduction of hydrogen sulfide inflow decreases the sulfur monoxide production rate, which in turn significantly affects the reactor temperature and the sulfur recovery rate. The more the oxygen that enters the reactor, the more the hydrogen sulfides that change into sulfur. American Chemical Society 2023-09-25 /pmc/articles/PMC10568715/ /pubmed/37841124 http://dx.doi.org/10.1021/acsomega.3c03065 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Eskandarzadeh, Hossein
Akbari, Ghasem
Yazdi, Mohammad Eftekhari
Lohrasbi Nichkoohi, Ali
Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas
title Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas
title_full Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas
title_fullStr Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas
title_full_unstemmed Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas
title_short Numerical Simulation of a High-Pressure Reactive Furnace in Recovering Sulfur from Sour Gas
title_sort numerical simulation of a high-pressure reactive furnace in recovering sulfur from sour gas
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10568715/
https://www.ncbi.nlm.nih.gov/pubmed/37841124
http://dx.doi.org/10.1021/acsomega.3c03065
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