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Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications

Novel multinary nanocomposite using solvothermal method synthesized and studied for their use in supercapacitors and photocatalysis to degrade pollutants using characterization techniques XRD, SEM, EDX, FTIR, Raman, UV–Vis, Zeta potential and photoluminescence spectroscopy whereas electrochemical te...

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Detalles Bibliográficos
Autores principales: Batool, Kiran, Rani, Malika, Rasool, Faisal, Karami, Abdulnasser M., Sillanpää, Mika, Shafique, Rubia, Akram, Mariam, Sohail, Amir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10569995/
https://www.ncbi.nlm.nih.gov/pubmed/37842602
http://dx.doi.org/10.1016/j.heliyon.2023.e20675
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author Batool, Kiran
Rani, Malika
Rasool, Faisal
Karami, Abdulnasser M.
Sillanpää, Mika
Shafique, Rubia
Akram, Mariam
Sohail, Amir
author_facet Batool, Kiran
Rani, Malika
Rasool, Faisal
Karami, Abdulnasser M.
Sillanpää, Mika
Shafique, Rubia
Akram, Mariam
Sohail, Amir
author_sort Batool, Kiran
collection PubMed
description Novel multinary nanocomposite using solvothermal method synthesized and studied for their use in supercapacitors and photocatalysis to degrade pollutants using characterization techniques XRD, SEM, EDX, FTIR, Raman, UV–Vis, Zeta potential and photoluminescence spectroscopy whereas electrochemical testing via EIS, CV and GCD analysis. Average crystalline size of 20.81 nm measured from XRD whereas EDX confirms GO suppression within nanocomposite. Mixed matrix like morphology is observable from SEM micrographs. The composite exhibited a band gap of 2.78 eV that could degrade MB dye at 94 % under direct sunlight consistent with first-order kinetics. Multiple distinctive peaks in FTIR spectra indicates various functional groups exsistence in the material alongwith zeta potential value of −17.9 mV. Raman spectra reveals D-band shifting to value 1361 cm(−1) while the G-band shifts to 1598 cm(−1) relative to GO. Furthermore electrochemical performance evaluated revealing electron transfer rate value 4.88 × 10(−9) cms(−1) with maximum capacitance about 7182 Fg(-1) at a scan rate of 10 mVs(−1) respectively. Power density ranges from 3591.18 to 2163 W/kg and energy density from 299 to 120 Wh/Kg as measured from GCD analysis. These findings indicates that novel multinary nanocomposite holds potential as an electrode material in supercapacitors and as a sunlight-driven photocatalyst for the degradation of water-borne organic pollutants.
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spelling pubmed-105699952023-10-14 Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications Batool, Kiran Rani, Malika Rasool, Faisal Karami, Abdulnasser M. Sillanpää, Mika Shafique, Rubia Akram, Mariam Sohail, Amir Heliyon Research Article Novel multinary nanocomposite using solvothermal method synthesized and studied for their use in supercapacitors and photocatalysis to degrade pollutants using characterization techniques XRD, SEM, EDX, FTIR, Raman, UV–Vis, Zeta potential and photoluminescence spectroscopy whereas electrochemical testing via EIS, CV and GCD analysis. Average crystalline size of 20.81 nm measured from XRD whereas EDX confirms GO suppression within nanocomposite. Mixed matrix like morphology is observable from SEM micrographs. The composite exhibited a band gap of 2.78 eV that could degrade MB dye at 94 % under direct sunlight consistent with first-order kinetics. Multiple distinctive peaks in FTIR spectra indicates various functional groups exsistence in the material alongwith zeta potential value of −17.9 mV. Raman spectra reveals D-band shifting to value 1361 cm(−1) while the G-band shifts to 1598 cm(−1) relative to GO. Furthermore electrochemical performance evaluated revealing electron transfer rate value 4.88 × 10(−9) cms(−1) with maximum capacitance about 7182 Fg(-1) at a scan rate of 10 mVs(−1) respectively. Power density ranges from 3591.18 to 2163 W/kg and energy density from 299 to 120 Wh/Kg as measured from GCD analysis. These findings indicates that novel multinary nanocomposite holds potential as an electrode material in supercapacitors and as a sunlight-driven photocatalyst for the degradation of water-borne organic pollutants. Elsevier 2023-10-04 /pmc/articles/PMC10569995/ /pubmed/37842602 http://dx.doi.org/10.1016/j.heliyon.2023.e20675 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Batool, Kiran
Rani, Malika
Rasool, Faisal
Karami, Abdulnasser M.
Sillanpää, Mika
Shafique, Rubia
Akram, Mariam
Sohail, Amir
Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications
title Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications
title_full Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications
title_fullStr Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications
title_full_unstemmed Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications
title_short Multinary nanocomposite of GO@SrO@CoCrO(3)@FeCr(2)O(4)@SnO(2)@SiO(2) for superior electrochemical performance and water purification applications
title_sort multinary nanocomposite of go@sro@cocro(3)@fecr(2)o(4)@sno(2)@sio(2) for superior electrochemical performance and water purification applications
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10569995/
https://www.ncbi.nlm.nih.gov/pubmed/37842602
http://dx.doi.org/10.1016/j.heliyon.2023.e20675
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