Highly Selective C(sp(3))–H Bond Oxygenation at Remote Methylenic Sites Enabled by Polarity Enhancement

[Image: see text] A detailed study on the C(sp(3))–H bond oxygenation reactions with H(2)O(2) catalyzed by the [Mn(OTf)(2)((TIPS)mcp)] complex at methylenic sites of cycloalkyl and 1-alkyl substrates bearing 19 different electron-withdrawing functional groups (EW FGs) was carried out. Oxidations in...

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Detalles Bibliográficos
Autores principales: Sisti, Sergio, Galeotti, Marco, Scarchilli, Filippo, Salamone, Michela, Costas, Miquel, Bietti, Massimo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10571082/
https://www.ncbi.nlm.nih.gov/pubmed/37751483
http://dx.doi.org/10.1021/jacs.3c07658

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10571082/
https://www.ncbi.nlm.nih.gov/pubmed/37751483
http://dx.doi.org/10.1021/jacs.3c07658

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