(31)P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus Bond Order

[Image: see text] We report the use of solution and solid-state (31)P Nuclear Magnetic Resonance (NMR) spectroscopy combined with Density Functional Theory calculations to benchmark the covalency of actinide-phosphorus bonds, thus introducing (31)P NMR spectroscopy to the investigation of molecular...

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Detalles Bibliográficos
Autores principales: Du, Jingzhen, Hurd, Joseph, Seed, John A., Balázs, Gábor, Scheer, Manfred, Adams, Ralph W., Lee, Daniel, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10571089/
https://www.ncbi.nlm.nih.gov/pubmed/37768555
http://dx.doi.org/10.1021/jacs.3c02775

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