Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap

A porous structure formed from sheets with cavities and two close packed structures were crystallised from building blocks prepared from 2,4-difluoronitrobenzene, a diamine linker and n-butylamine. The porous structure crystallised from a flexible building block prepared using 1,4-diaminobutane as l...

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Detalles Bibliográficos
Autores principales: Plater, M. John, Esslemont, Abbie J., Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10572935/
https://www.ncbi.nlm.nih.gov/pubmed/37834130
http://dx.doi.org/10.3390/ijms241914683
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author Plater, M. John
Esslemont, Abbie J.
Harrison, William T. A.
author_facet Plater, M. John
Esslemont, Abbie J.
Harrison, William T. A.
author_sort Plater, M. John
collection PubMed
description A porous structure formed from sheets with cavities and two close packed structures were crystallised from building blocks prepared from 2,4-difluoronitrobenzene, a diamine linker and n-butylamine. The porous structure crystallised from a flexible building block prepared using 1,4-diaminobutane as linker. The close packed structures were prepared using either piperazine or 1,4-bis(aminomethyl)benzene as a linker and have less conformational freedom.
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spelling pubmed-105729352023-10-14 Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap Plater, M. John Esslemont, Abbie J. Harrison, William T. A. Int J Mol Sci Article A porous structure formed from sheets with cavities and two close packed structures were crystallised from building blocks prepared from 2,4-difluoronitrobenzene, a diamine linker and n-butylamine. The porous structure crystallised from a flexible building block prepared using 1,4-diaminobutane as linker. The close packed structures were prepared using either piperazine or 1,4-bis(aminomethyl)benzene as a linker and have less conformational freedom. MDPI 2023-09-28 /pmc/articles/PMC10572935/ /pubmed/37834130 http://dx.doi.org/10.3390/ijms241914683 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Plater, M. John
Esslemont, Abbie J.
Harrison, William T. A.
Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap
title Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap
title_full Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap
title_fullStr Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap
title_full_unstemmed Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap
title_short Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an n-Butylamine Cap
title_sort porous and close packed supramolecular assemblies from 2,4-difluoronitrobenzene with three different linkers and an n-butylamine cap
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10572935/
https://www.ncbi.nlm.nih.gov/pubmed/37834130
http://dx.doi.org/10.3390/ijms241914683
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