Cargando…

Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties

Polyhedral oligomeric silsesquioxanes (POSS) and hybrid organo-halide perovskites are two important types of hybrid nanoscale frameworks with great potential in materials chemistry. Both are currently under intensive investigation for a wide range of possible applications. Recent results suggest tha...

Descripción completa

Detalles Bibliográficos
Autores principales: Kowalewska, Anna, Majewska-Smolarek, Kamila
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10573911/
https://www.ncbi.nlm.nih.gov/pubmed/37834668
http://dx.doi.org/10.3390/ma16196531
_version_ 1785120571203256320
author Kowalewska, Anna
Majewska-Smolarek, Kamila
author_facet Kowalewska, Anna
Majewska-Smolarek, Kamila
author_sort Kowalewska, Anna
collection PubMed
description Polyhedral oligomeric silsesquioxanes (POSS) and hybrid organo-halide perovskites are two important types of hybrid nanoscale frameworks with great potential in materials chemistry. Both are currently under intensive investigation for a wide range of possible applications. Recent results suggest that POSS can be attractive passivating and structure-controlling agents for perovskite materials. In this review, we present the importance of POSS in engineering the structures of inorganic cesium-halide perovskites CsPbX(3) (X = Cl, Br, I) to create a new class of hybrid derivatives with improved properties. The combination of these two components can be an effective strategy for controlling the perovskite crystallization process. In addition, passivation of surface defects/bulk and the engineering of energy and optoelectronic properties of perovskite-based materials can be achieved following this method. In this minireview, we summarized the existing literature reports on the structural specificity and properties of hybrid POSS perovskites.
format Online
Article
Text
id pubmed-10573911
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-105739112023-10-14 Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties Kowalewska, Anna Majewska-Smolarek, Kamila Materials (Basel) Review Polyhedral oligomeric silsesquioxanes (POSS) and hybrid organo-halide perovskites are two important types of hybrid nanoscale frameworks with great potential in materials chemistry. Both are currently under intensive investigation for a wide range of possible applications. Recent results suggest that POSS can be attractive passivating and structure-controlling agents for perovskite materials. In this review, we present the importance of POSS in engineering the structures of inorganic cesium-halide perovskites CsPbX(3) (X = Cl, Br, I) to create a new class of hybrid derivatives with improved properties. The combination of these two components can be an effective strategy for controlling the perovskite crystallization process. In addition, passivation of surface defects/bulk and the engineering of energy and optoelectronic properties of perovskite-based materials can be achieved following this method. In this minireview, we summarized the existing literature reports on the structural specificity and properties of hybrid POSS perovskites. MDPI 2023-10-01 /pmc/articles/PMC10573911/ /pubmed/37834668 http://dx.doi.org/10.3390/ma16196531 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Kowalewska, Anna
Majewska-Smolarek, Kamila
Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties
title Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties
title_full Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties
title_fullStr Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties
title_full_unstemmed Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties
title_short Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties
title_sort hybrid perovskite-based materials modified with polyhedral silsesquioxanes—structure and properties
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10573911/
https://www.ncbi.nlm.nih.gov/pubmed/37834668
http://dx.doi.org/10.3390/ma16196531
work_keys_str_mv AT kowalewskaanna hybridperovskitebasedmaterialsmodifiedwithpolyhedralsilsesquioxanesstructureandproperties
AT majewskasmolarekkamila hybridperovskitebasedmaterialsmodifiedwithpolyhedralsilsesquioxanesstructureandproperties