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Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties
Polyhedral oligomeric silsesquioxanes (POSS) and hybrid organo-halide perovskites are two important types of hybrid nanoscale frameworks with great potential in materials chemistry. Both are currently under intensive investigation for a wide range of possible applications. Recent results suggest tha...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10573911/ https://www.ncbi.nlm.nih.gov/pubmed/37834668 http://dx.doi.org/10.3390/ma16196531 |
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author | Kowalewska, Anna Majewska-Smolarek, Kamila |
author_facet | Kowalewska, Anna Majewska-Smolarek, Kamila |
author_sort | Kowalewska, Anna |
collection | PubMed |
description | Polyhedral oligomeric silsesquioxanes (POSS) and hybrid organo-halide perovskites are two important types of hybrid nanoscale frameworks with great potential in materials chemistry. Both are currently under intensive investigation for a wide range of possible applications. Recent results suggest that POSS can be attractive passivating and structure-controlling agents for perovskite materials. In this review, we present the importance of POSS in engineering the structures of inorganic cesium-halide perovskites CsPbX(3) (X = Cl, Br, I) to create a new class of hybrid derivatives with improved properties. The combination of these two components can be an effective strategy for controlling the perovskite crystallization process. In addition, passivation of surface defects/bulk and the engineering of energy and optoelectronic properties of perovskite-based materials can be achieved following this method. In this minireview, we summarized the existing literature reports on the structural specificity and properties of hybrid POSS perovskites. |
format | Online Article Text |
id | pubmed-10573911 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-105739112023-10-14 Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties Kowalewska, Anna Majewska-Smolarek, Kamila Materials (Basel) Review Polyhedral oligomeric silsesquioxanes (POSS) and hybrid organo-halide perovskites are two important types of hybrid nanoscale frameworks with great potential in materials chemistry. Both are currently under intensive investigation for a wide range of possible applications. Recent results suggest that POSS can be attractive passivating and structure-controlling agents for perovskite materials. In this review, we present the importance of POSS in engineering the structures of inorganic cesium-halide perovskites CsPbX(3) (X = Cl, Br, I) to create a new class of hybrid derivatives with improved properties. The combination of these two components can be an effective strategy for controlling the perovskite crystallization process. In addition, passivation of surface defects/bulk and the engineering of energy and optoelectronic properties of perovskite-based materials can be achieved following this method. In this minireview, we summarized the existing literature reports on the structural specificity and properties of hybrid POSS perovskites. MDPI 2023-10-01 /pmc/articles/PMC10573911/ /pubmed/37834668 http://dx.doi.org/10.3390/ma16196531 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Kowalewska, Anna Majewska-Smolarek, Kamila Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties |
title | Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties |
title_full | Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties |
title_fullStr | Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties |
title_full_unstemmed | Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties |
title_short | Hybrid Perovskite-Based Materials Modified with Polyhedral Silsesquioxanes—Structure and Properties |
title_sort | hybrid perovskite-based materials modified with polyhedral silsesquioxanes—structure and properties |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10573911/ https://www.ncbi.nlm.nih.gov/pubmed/37834668 http://dx.doi.org/10.3390/ma16196531 |
work_keys_str_mv | AT kowalewskaanna hybridperovskitebasedmaterialsmodifiedwithpolyhedralsilsesquioxanesstructureandproperties AT majewskasmolarekkamila hybridperovskitebasedmaterialsmodifiedwithpolyhedralsilsesquioxanesstructureandproperties |